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Systematic Study of Perovskite Layers if Doped with Strong Oxidants
Wang, Dan,; Cui, Rongli; Guo, Xihong; Huang, Huan; Liu, Bing; Wang, Dong-Mei,; Qi, Weiheng,; Chen, Yu; Zheng, Lirong; Zhang, Jing; Liu, Shuhu; Dong, Jinquan; Sun, Baoyun,
2022
发表期刊Solar RRL
ISSN2367-198X
EISSN2367198X
卷号6期号:8页码:2200159
条目编号IHEP00035085
文章类型Article
摘要Herein, strong oxidants are employed for the first time to stabilize the main frame structure of the perovskite [PbI6]4− by strengthening the interaction between the central Pb atom and coordination I atoms. A systematic study on the microstructure and macrostate of the perovskite is carried out by the synchrotron radiation technique and conventional characterization. According to the valence state and local environment of each chemical element, crystallinity and morphology of the active layer, and photoelectric properties of the solar cell, the strong oxidants, tris[2-((1H-pyrazol-1-yl)-4-tert-butylpyridine)cobalt(III)tris(bis(trifluoromethylsulfonyl)imide)] (FK209) and Na2S2O8, can increase the power conversion efficiency and stability of the doped devices. A possible mechanism of doping strong oxidants is explained. © 2022 Wiley-VCH GmbH.
DOI10.1002/solr.202200159
语种英语
WOS记录号WOS:000792053000001
EI主题词Crystallinity - Synchrotron radiation - Chemical elements - Morphology - Chemical stability - Perovskite solar cells - Cobalt compounds - Sodium compounds
EI分类号482.2 Minerals - 702.3 Solar Cells - 801 Chemistry - 804 Chemical Products Generally - 931.2 Physical Properties of Gases, Liquids and Solids - 932.1.1 Particle Accelerators - 933.1 Crystalline Solids - 951 Materials Science
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文献类型期刊论文
条目标识符https://ir.ihep.ac.cn/handle/311005/300381
专题多学科研究中心
加速器中心
作者单位中国科学院高能物理研究所
第一作者单位中国科学院高能物理研究所
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Wang, Dan,,Cui, Rongli,Guo, Xihong,et al. Systematic Study of Perovskite Layers if Doped with Strong Oxidants[J]. Solar RRL,2022,6(8):2200159.
APA Wang, Dan,.,Cui, Rongli.,Guo, Xihong.,Huang, Huan.,Liu, Bing.,...&Sun, Baoyun,.(2022).Systematic Study of Perovskite Layers if Doped with Strong Oxidants.Solar RRL,6(8),2200159.
MLA Wang, Dan,,et al."Systematic Study of Perovskite Layers if Doped with Strong Oxidants".Solar RRL 6.8(2022):2200159.
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