Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst

doi:10.1002/chem.201804284

	Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst
	Hu KQ(胡孔球); Huang ZW(黄志伟); Zhang ZH(张致慧); Mei L(梅雷); Yu JP(于吉攀); Chai ZF(柴之芳); Shi WQ(石伟群); Hu, Kong-Qiu; Huang, Zhi-Wei; Zhang, Zhi-Hui; Mei, Lei; Qian, Bing-Bing; Yu, Ji-Pan; Chai, Zhi-Fang; Shi, Wei-Qun
	2018
发表期刊	CHEMISTRY-A EUROPEAN JOURNAL (IF:5.317[JCR-2016],5.184[5-Year])
ISSN	0947-6539
EISSN	1521-3765
卷号	24 期号:63 页码:16766-16769
文章类型	Article
摘要	Uranyl-organic frameworks (UOFs) have recently been the object of many research endeavors due to the unique coordination mode of uranyl ions and their attractive physicochemical properties. Here, a new (3,4)-connected UOF (U-IHEP-4) assembled from uranyl and porphyrin ligand tetrakis(4-carboxyphenyl)porphyrin (H4TCPP) is reported, which represents the first case of actinide porphyrinic MOFs. Adsorption experiments in DMF solution demonstrated that U-IHEP-4 selectively adsorbs positively charged dyes, which is in line with its negatively charged framework and large pore volume ratio (90 %). Remarkably, U-IHEP-4 exhibited high catalytic activity for the dehydrogenation of N-heterocycles to synthesize the corresponding aromatic heterocycles and it can be used as an efficient heterogeneous catalyst.
关键词	actinides catalyst porphyrins selective dye adsorption uranyl-organic frameworks
DOI	10.1002/chem.201804284
关键词[WOS]	METAL-ORGANIC FRAMEWORKS ; COORDINATION POLYMERS ; CARBENE INSERTION ; HIGHLY EFFICIENT ; RATIONAL DESIGN ; N-HETEROCYCLES ; URANIUM ; TOPOLOGY ; CRYSTAL ; CONSTRUCTION
收录类别	SCI ; EI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000450258500010
EI入藏号	20184406002715
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://ir.ihep.ac.cn/handle/311005/286880
专题	中国科学院高能物理研究所_中国散裂中子源多学科研究中心
通讯作者	Shi WQ(石伟群)
作者单位	中国科学院高能物理研究所
第一作者单位	中国科学院高能物理研究所
通讯作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Hu KQ,Huang ZW,Zhang ZH,et al. Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst[J]. CHEMISTRY-A EUROPEAN JOURNAL,2018,24(63):16766-16769.
APA	胡孔球.,黄志伟.,张致慧.,梅雷.,于吉攀.,...&Shi, Wei-Qun.(2018).Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst.CHEMISTRY-A EUROPEAN JOURNAL,24(63),16766-16769.
MLA	胡孔球,et al."Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst".CHEMISTRY-A EUROPEAN JOURNAL 24.63(2018):16766-16769.