Tertiary structure of cactus-like WO3 spheres self-assembled on Cu foil for supercapacitive electrode materials

doi:10.1016/j.jallcom.2017.04.094

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	Tertiary structure of cactus-like WO3 spheres self-assembled on Cu foil for supercapacitive electrode materials
	Zheng, F; Gong, HQ; Li, Z; Yang, WG; Xu, JH; Hu, PF; Li, Y; Gong, Y; Zhen, Q; Gong Y(宫宇)
	2017
发表期刊	JOURNAL OF ALLOYS AND COMPOUNDS (IF:3.133[JCR-2016],2.919[5-Year])
ISSN	0925-8388
EISSN	1873-4669
卷号	712 页码:345-354
文章类型	Article
摘要	WO3 microspheres film with a tertiary, textured and porous structure assembled of WO3 hierarchical nanorods has been directly prepared on Cu foil using a one-step hydrothermal method. The field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) spectrum, X-Ray Diffraction (XRD), high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS) are used to reveal the surface microtopography, crystal structure, elementary composition, valence state and formation mechanism of WO3 tertiary structure. Moreover, the electro-chemical properties and supercapacitive performances of WO3 microspheres film are also intensively investigated. The WO3 microspheres film has high specific capacitances of 485, 426, 372, 319 and 260 F g(-1) at unit currents of 0.5, 1, 2, 5 and 10 A g(-1) and exhibits good cycle stability (93% after 5000 cycles) and reversibility (98.5%), a lower charge transfer resistance (0.5 Omega) and high energy densities ranging from 21 to 17 W h kg(-1) corresponded to high power densities varied from 150 to 3000 W kg(-1). (C) 2017 Elsevier B.V. All rights reserved.
关键词	Tungsten trioxide Tertiary structure Nanorods Supercapacitor
DOI	10.1016/j.jallcom.2017.04.094
关键词[WOS]	HIGH-PERFORMANCE SUPERCAPACITORS ; AQUEOUS HYBRID SUPERCAPACITOR ; CARBON NANOFIBER COMPOSITES ; TUNGSTEN-OXIDE ; ENERGY-STORAGE ; ACTIVATED CARBON ; GRAPHENE ; CAPACITANCE ; FILMS
收录类别	SCI ; EI ; SCOPUS
语种	英语
WOS研究方向	Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000401881000044
EI入藏号	20171603579686
EI主题词	Charge transfer - Copper - Crystal structure - Field emission microscopes - High resolution transmission electron microscopy - Metal cladding - Microspheres - Nanorods - Scanning electron microscopy - Supercapacitor - Tungsten compounds - X ray diffraction
EI分类号	544.1 Copper - 741.3 Optical Devices and Systems - 761 Nanotechnology - 802.2 Chemical Reactions - 933 Solid State Physics - 933.1.1 Crystal Lattice
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://ir.ihep.ac.cn/handle/311005/285207
专题	多学科研究中心
作者单位	中国科学院高能物理研究所
第一作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Zheng, F,Gong, HQ,Li, Z,et al. Tertiary structure of cactus-like WO3 spheres self-assembled on Cu foil for supercapacitive electrode materials[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2017,712:345-354.
APA	Zheng, F.,Gong, HQ.,Li, Z.,Yang, WG.,Xu, JH.,...&宫宇.(2017).Tertiary structure of cactus-like WO3 spheres self-assembled on Cu foil for supercapacitive electrode materials.JOURNAL OF ALLOYS AND COMPOUNDS,712,345-354.
MLA	Zheng, F,et al."Tertiary structure of cactus-like WO3 spheres self-assembled on Cu foil for supercapacitive electrode materials".JOURNAL OF ALLOYS AND COMPOUNDS 712(2017):345-354.