The VUV luminescence properties and the Ce3+-> Tb3+ energy transfer in the (Sr, ba) Al12O19

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	The VUV luminescence properties and the Ce3+-> Tb3+ energy transfer in the (Sr, ba) Al12O19
	Mang, ZY; Zhang, YH; Li, XL; Shen, LJ; Han, L; Zhou, YB; Xu, JH; Huang, Y; Xu JH(徐建华); Huang Y(黄艳)
	2008
发表期刊	SPECTROSCOPY AND SPECTRAL ANALYSIS
卷号	28 期号:8 页码:1737-1740
通讯作者	[Mang Zhong-yi ; Zhang Yun-hong] Beijing Inst Technol, Inst Chem Phys, Beijing 100081, Peoples R China ; [Mang Zhong-yi ; Li Xiau-li ; Shen Lei-jun ; Han Li ; Zhou Yong-bo ; Xu Jian-hua] Baotou Res Inst Rare Earth, Baotou 014030, Peoples R China ; [Huang Yan] Chinese Acad Sci, Inst High Energy Phys, Lab Beijing Synchrotron Radiat, Beijing 100039, Peoples R China
摘要	The (Sr, Ba) Al12O19 : RE3+ (RE=Ce, Tb) compounds have been synthesized by the solid state reaction technology. The single-phase magnetoplumbite-type crystal structure has been identified by the X-ray diffraction analysis. The 302 rim peak and similar to 340 nm not-clear shoulder are correspondence to the 5d -> F-2(5/2) and 5d -> F-2(7/2) transitions in the emission spectrum, respectively. The 158 rim peak and 260 nm peak are separately contributed to the host absorption and 4f-5d transition of Ce3+ in the excitation spectrum. The characteristic emission of D-5(3)-> F-7(j) (j = 2, 3, 4, 5) and D-5(4)-> F-7(j) (j = 4, 5, 6) transitions in the range of 400-600 nm are assigned in the emission spectrum of (Sr, Ba)Al12O19 : Tb-0.05(3+). The similar to 160 nm peaks arises from the overlap of the Tb3+-O2- charge transfer band and the host absorption. The 193 nm and 233 nm peaks are attributed by the spin-allowed 4f-5d transition and the spin-forbidden transition, respectively. The overlap between the emission of Ce3+ and the f-f transition absorption of Tb3+ exists in the (Sr, Ba)Al12O19 : Tb3+, Ce3+ compounds. The luminescence intensity of Tb 31 increases with the increase of the Ce3+ ion concentration. When the Ce3+ ion concentration reaches about 0.03 mole, the luminescence intensity of Tb3+ ion is nearly two times comparing with the non-codoping Ce3+ ion compounds. When the emission wavelength is 543 run, the excitation spectra exhibit the 4f-5d absorption of Ce3+ besides the host absorption and 4f-5d transitions of Tb3+ in the (Sr, Ba)Al12O19 : Tb3+, Ce3+ compounds. According to the excitation spectrum, the part of the emission of Tb 31 comes from the absorption of Ce3+ ion. Therefore, it is illustrated that the Ce3+-> Tb3+ energy transfer has been existed in the (Sr, Ba)Al12O19 : RE3+ (RE=Ce, Tb) compounds.
文章类型	Article
关键词	(Sr, Ba) Al12O17 Ce3+ and Tb3+ VUV energy transfer
学科领域	Spectroscopy
研究领域[WOS]	Spectroscopy
URL	查看原文
语种	英语
WOS类目	Spectroscopy
WOS记录号	WOS:000258968500011
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.ihep.ac.cn/handle/311005/239501
专题	多学科研究中心核技术应用研究中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Mang, ZY,Zhang, YH,Li, XL,et al. The VUV luminescence properties and the Ce3+-> Tb3+ energy transfer in the (Sr, ba) Al12O19[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2008,28(8):1737-1740.
APA	Mang, ZY.,Zhang, YH.,Li, XL.,Shen, LJ.,Han, L.,...&黄艳.(2008).The VUV luminescence properties and the Ce3+-> Tb3+ energy transfer in the (Sr, ba) Al12O19.SPECTROSCOPY AND SPECTRAL ANALYSIS,28(8),1737-1740.
MLA	Mang, ZY,et al."The VUV luminescence properties and the Ce3+-> Tb3+ energy transfer in the (Sr, ba) Al12O19".SPECTROSCOPY AND SPECTRAL ANALYSIS 28.8(2008):1737-1740.

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