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Estimation of the composition of intermetallic compounds in LiCl-KCl molten salt by cyclic voltammetry
Liu YL(刘雅兰); Liu K(刘奎); Yuan LY(袁立永); Chai ZF(柴之芳); Shi WQ(石伟群); Liu, YL; Liu, K; Yuan, LY; Chai, ZF; Shi, WQ
2016
Source PublicationFARADAY DISCUSSIONS
ISSN1359-6640
EISSN1364-5498
Volume190Pages:387-398
Corresponding Author石伟群
SubtypeArticle
AbstractIn this work, the compositions of Ce-Al, Er-Al and La-Bi intermetallic compounds were estimated by the cyclic voltammetry (CV) technique. At first, CV measurements were carried out at different reverse potentials to study the co-reduction processes of Ce-Al, Er-Al and La-Bi systems. The CV curves obtained were then re-plotted with the current as a function of time, and the coulomb number of each peak was calculated. By comparing the coulomb number of the related peaks, the compositions of the Ce-Al, Er-Al and La-Bi intermetallic compounds formed in the co-reduction process could be estimated. The results showed that Al11Ce3, Al3Ce, Al2Ce and AlCe could be formed by the co-reduction of Ce(III) and Al(III). For the co-reduction of Er(III) and Al(III), Al3Er2, Al2Er and AlEr were formed. In a La(III) and Bi(III) co-existing system in LiCl-KCl melts, LaBi2, LaBi and Li3Bi were the major products as a result of co-reduction.
DOI10.1039/c5fd00220f
WOS KeywordSOLID ALUMINUM CATHODES ; THERMOCHEMICAL PROPERTIES ; ELECTROCHEMICAL-BEHAVIOR ; THERMODYNAMIC PROPERTIES ; CO-REDUCTION ; ACTINIDES ; SEPARATION ; ELECTRODE ; LIQUID ; LANTHANIDES
Indexed BySCI ; ADS ; ADS
Language英语
WOS IDWOS:000381495600023
ADS Bibcode2016FaDi..190..387L
ADS URLhttps://ui.adsabs.harvard.edu/abs/2016FaDi..190..387L
ADS CITATIONShttps://ui.adsabs.harvard.edu/abs/2016FaDi..190..387L/citations
Citation statistics
Cited Times:2 [ADS]
Document Type期刊论文
Identifierhttp://ir.ihep.ac.cn/handle/311005/261080
Collection院士
多学科研究中心
Affiliation中国科学院高能物理研究所
Recommended Citation
GB/T 7714
Liu YL,Liu K,Yuan LY,et al. Estimation of the composition of intermetallic compounds in LiCl-KCl molten salt by cyclic voltammetry[J]. FARADAY DISCUSSIONS,2016,190:387-398.
APA 刘雅兰.,刘奎.,袁立永.,柴之芳.,石伟群.,...&Shi, WQ.(2016).Estimation of the composition of intermetallic compounds in LiCl-KCl molten salt by cyclic voltammetry.FARADAY DISCUSSIONS,190,387-398.
MLA 刘雅兰,et al."Estimation of the composition of intermetallic compounds in LiCl-KCl molten salt by cyclic voltammetry".FARADAY DISCUSSIONS 190(2016):387-398.
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