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Effects of Activation Atmospheres on Structure and Activity of Mo-based Catalyst for Synthesis of Higher Alcohols
Alternative Title活化气氛对钼基合成醇催化剂的结构和性能的影响
Zhou, JL; Xie, W; Sun, S; Ji, LL; Zheng, LR; Gao, C; Bao, J; Zheng LR(郑黎荣)
2016
Source PublicationCHINESE JOURNAL OF CHEMICAL PHYSICS
ISSN1674-0068
EISSN1003-7713
Volume29Issue:4Pages:467-473
SubtypeArticle
AbstractActivated carbon supported Mo-based catalysts were prepared and reduced under different activation atmospheres, including pure H-2, syngas (H-2/CO=2/1), and pure CO. The catalysts structures were characterized by X-ray diffraction, X-ray absorption fine structure, and in situ diffuse reflectance infrared Fourier transform spectroscopy. The catalytic performance for the higher alcohol synthesis from syngas was tested. The pure H-2 treatment showed a high reduction capacity. The presence of a large amount of metallic Co-0 and low valence state Mo phi+ (0
KeywordHigher alcohol synthesis Activation mechanism in situ diffuse reflectance infrared Fourier transform spectroscopy Mo-based catalyst Syngas
DOI10.1063/1674-0068/29/cjcp1603038
WOS KeywordFISCHER-TROPSCH CATALYSTS ; DIFFUSE-REFLECTANCE FTIR ; CO HYDROGENATION ; SYNTHESIS GAS ; SYNGAS ADSORPTION ; COBALT CATALYSTS ; CARBON NANOTUBES ; MOLYBDENUM ; CONVERSION ; PROMOTER
Indexed BySCI ; ADS
Language英语
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS IDWOS:000383114400010
ADS Bibcode2016ChJCP..29..467Z
ADS URLhttps://ui.adsabs.harvard.edu/abs/2016ChJCP..29..467Z
ADS CITATIONShttps://ui.adsabs.harvard.edu/abs/2016ChJCP..29..467Z/citations
Citation statistics
Cited Times:0 [ADS]
Document Type期刊论文
Identifierhttp://ir.ihep.ac.cn/handle/311005/260423
Collection中国科学院高能物理研究所
Affiliation中国科学院高能物理研究所
Recommended Citation
GB/T 7714
Zhou, JL,Xie, W,Sun, S,et al. Effects of Activation Atmospheres on Structure and Activity of Mo-based Catalyst for Synthesis of Higher Alcohols[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2016,29(4):467-473.
APA Zhou, JL.,Xie, W.,Sun, S.,Ji, LL.,Zheng, LR.,...&郑黎荣.(2016).Effects of Activation Atmospheres on Structure and Activity of Mo-based Catalyst for Synthesis of Higher Alcohols.CHINESE JOURNAL OF CHEMICAL PHYSICS,29(4),467-473.
MLA Zhou, JL,et al."Effects of Activation Atmospheres on Structure and Activity of Mo-based Catalyst for Synthesis of Higher Alcohols".CHINESE JOURNAL OF CHEMICAL PHYSICS 29.4(2016):467-473.
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