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Phosphine-Catalyzed Enantioselective [4+3] Annulation of Allenoates with C,N-Cyclic Azomethine Imines: Synthesis of Quinazoline-Based Tricyclic Heterocycles
Yuan, CH; Zhou, LJ; Xia MR(夏苗仁); Wang DQ(王东琪); Xia, MR; Sun, ZH; Wang, DQ; Guo, HC
2016
发表期刊ORGANIC LETTERS
卷号18期号:21页码:5644-5647
文章类型期刊论文
摘要With the use of a commercially available chiral phosphine as the catalyst, the first catalytic enantioselective [4 + 3] annulation of allenoates with C,N-cyclic azomethine imines is developed. The reaction works efficiently under mild reaction conditions to afford seven-membered ring-fused quinazoline-based tricyclic heterocycles in high yields with good to excellent diastereo- and enantioselectivities.
DOI10.1021/acs.orglett.6b02885
关键词[WOS]DEMAND 1,3-DIPOLAR CYCLOADDITION ; BAYLIS-HILLMAN CARBONATES ; 7-MEMBERED RINGS ; ALDEHYDES ; ALKYNES ; YLIDES ; 1,2-DIAZEPINES ; ALKALOIDS ; CHEMISTRY ; STRATEGY
语种英语
WOS类目Chemistry, Organic
WOS记录号WOS:000387303200050
引用统计
被引频次:18[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/260414
专题多学科研究中心
作者单位中国科学院高能物理研究所
推荐引用方式
GB/T 7714
Yuan, CH,Zhou, LJ,Xia MR,et al. Phosphine-Catalyzed Enantioselective [4+3] Annulation of Allenoates with C,N-Cyclic Azomethine Imines: Synthesis of Quinazoline-Based Tricyclic Heterocycles[J]. ORGANIC LETTERS,2016,18(21):5644-5647.
APA Yuan, CH.,Zhou, LJ.,夏苗仁.,王东琪.,Xia, MR.,...&Guo, HC.(2016).Phosphine-Catalyzed Enantioselective [4+3] Annulation of Allenoates with C,N-Cyclic Azomethine Imines: Synthesis of Quinazoline-Based Tricyclic Heterocycles.ORGANIC LETTERS,18(21),5644-5647.
MLA Yuan, CH,et al."Phosphine-Catalyzed Enantioselective [4+3] Annulation of Allenoates with C,N-Cyclic Azomethine Imines: Synthesis of Quinazoline-Based Tricyclic Heterocycles".ORGANIC LETTERS 18.21(2016):5644-5647.
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