Metal-responsive activation of C-O and C-C bonds of an aromatic vicinal diol in hydrothermal conditions: synthesis, structure, mechanism and magnetic properties
Feng, SS; Zheng, JF; Lu, LP; Lu, HG; Gao, ZQ; Dong, YH; Gao ZQ(高增强); Dong YH(董宇辉)
刊名CRYSTENGCOMM
2016
卷号18期号:47页码:9077-9084
DOI10.1039/c6ce01708h
文章类型期刊论文
英文摘要The selective in situ reactions of 1,2-di(1H-benzimidazol-2-yl) ethane-1,2-diol (TDB) in the presence of 3d transition-metal ions under hydrothermal conditions were investigated. The research demonstrated that divalent Fe, Co, and Ni salts are apt to cause the intramolecular dehydration of TDB, then form pentanuclear [M-5(H2L)(6)](4+) clusters, and Cu cations tend to activate specific C-C bonds, then give rise to benzimidazole derivatives and the corresponding copper(I/II) complexes. The results illuminate that reaction temperature and pressure are necessary conditions for molecular rearrangement and the radii and valence state of metal ions are key factors in the metal-responsive decomposition of TDB. Based on the results, the corresponding mechanism is proposed. Moreover, the synthesis, crystal structure, thermal stability and magnetism of related complexes are investigated.
类目[WOS]Chemistry, Multidisciplinary ; Crystallography
关键词[WOS]COORDINATION POLYMERS ; LIGAND ; COMPLEXES ; CLUSTERS ; BIOMASS ; STATE ; ACID
语种英语
WOS记录号WOS:000392449800012
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/260379
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
中国科学院高能物理研究所_多学科研究中心
作者单位中国科学院高能物理研究所
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GB/T 7714
Feng, SS,Zheng, JF,Lu, LP,et al. Metal-responsive activation of C-O and C-C bonds of an aromatic vicinal diol in hydrothermal conditions: synthesis, structure, mechanism and magnetic properties[J]. CRYSTENGCOMM,2016,18(47):9077-9084.
APA Feng, SS.,Zheng, JF.,Lu, LP.,Lu, HG.,Gao, ZQ.,...&董宇辉.(2016).Metal-responsive activation of C-O and C-C bonds of an aromatic vicinal diol in hydrothermal conditions: synthesis, structure, mechanism and magnetic properties.CRYSTENGCOMM,18(47),9077-9084.
MLA Feng, SS,et al."Metal-responsive activation of C-O and C-C bonds of an aromatic vicinal diol in hydrothermal conditions: synthesis, structure, mechanism and magnetic properties".CRYSTENGCOMM 18.47(2016):9077-9084.
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