The status of molybdenum ions in the lead dioxide-lead glasses and vitroceramics
Suciu, RC; Rada, M; Culea, E; Biris, A; Rada, S; Leostean, C; Suciu, M; Marian, I; Wu, ZH; Jing, Z; Wu ZH(吴忠华); Zhang J(张静)
刊名JOURNAL OF NON-CRYSTALLINE SOLIDS
2016
卷号453页码:36-41
关键词xMoO(3)center dot(100-x)[4PbO(2)center dot Pb] glasses and vitroceramics Pb2MoO5 XRD SEM Raman Photoluminescence and XPS spectroscopies
DOI10.1016/j.jnoncrysol.2016.09.024
文章类型期刊论文
英文摘要Glasses and vitroceramics in the xMoO(3)center dot(100 - x)[4PbO(2)center dot Pb] system with x = 5-50 mol%MoO3 were prepared by melt quenching method. The influence of MoO3 content on optical properties and structure of the 4PbO(2)center dot Pb host network was investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman, photofluorescence and X-ray photoelectron (XPS) spectroscopies. The X-ray patterns show the presence of a small amount of Pb2MoO5 crystalline phase in the sample with x = 40 mol%MoO3. By increasing of MoO3 content up to 50 mol% MoO3, Pb2MoO5 and tetragonal PbO crystalline phases were detected. Raman data show the bending modes of the O-Pb-O linkages which allow the intercalation of [PbO4] structural units, isolated [MoO4] and deformed [MoO6] structural units as basic structural units formed by lead and molybdenum atoms. The photofluorescence spectroscopy data shows the transitions of Mo+5 and Pb2+ ions. According to the XPS data, the vitroceramic network contains mainly [MoO4] tetrahedral units and small amounts of [MoO6] octahedral units. (C) 2016 Elsevier B.V. All rights reserved.
类目[WOS]Materials Science, Ceramics ; Materials Science, Multidisciplinary
关键词[WOS]X-RAY-DIFFRACTION ; ELECTRONIC-STRUCTURE ; PB2MOO5 ; SPECTROSCOPY ; CRYSTAL ; PBMOO4 ; PBO ; PROGRAM ; SURFACE ; SYSTEM
语种英语
WOS记录号WOS:000388057600006
引用统计
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/260362
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
作者单位中国科学院高能物理研究所
推荐引用方式
GB/T 7714
Suciu, RC,Rada, M,Culea, E,et al. The status of molybdenum ions in the lead dioxide-lead glasses and vitroceramics[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS,2016,453:36-41.
APA Suciu, RC.,Rada, M.,Culea, E.,Biris, A.,Rada, S.,...&张静.(2016).The status of molybdenum ions in the lead dioxide-lead glasses and vitroceramics.JOURNAL OF NON-CRYSTALLINE SOLIDS,453,36-41.
MLA Suciu, RC,et al."The status of molybdenum ions in the lead dioxide-lead glasses and vitroceramics".JOURNAL OF NON-CRYSTALLINE SOLIDS 453(2016):36-41.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
20160868.pdf(986KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Suciu, RC]的文章
[Rada, M]的文章
[Culea, E]的文章
百度学术
百度学术中相似的文章
[Suciu, RC]的文章
[Rada, M]的文章
[Culea, E]的文章
必应学术
必应学术中相似的文章
[Suciu, RC]的文章
[Rada, M]的文章
[Culea, E]的文章
相关权益政策
暂无数据
收藏/分享
文件名: 20160868.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。