High Pressure Behavior of Hydrogen Storage Material Guanidinium Borohydride
Qi, GY; Wang, K; Li XD(李晓东); Li, XD; Zou, B
刊名JOURNAL OF PHYSICAL CHEMISTRY C
2016
卷号120期号:25页码:13414-13420
DOI10.1021/acs.jpcc.6b04154
文章类型期刊论文
英文摘要A combination of synchrotron powder angle-dispersive X-ray diffraction (ADXRD) and Raman spectroscopy has been utilized to study high pressure behavior of the chemical hydrogen storage material guanidinium borohydride (GBH) [C(NH2)(3)] [BH4](-). A reversible structural phase transition was observed at approximately 0.4 GPa, evidenced by the obvious changes in ADXRD patterns and Raman spectra. Both Raman spectra and the first-principles calculation revealed that new dihydrogen bonds generated under high pressure, which was proposed to be the reason for the observed phase transition. This research explored the pressure induced changes of GBH and studied the evolution of dihydrogen bonds, which can give insight into the improvement of the hydrogen release properties.
类目[WOS]Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
关键词[WOS]INDUCED PHASE-TRANSITION ; AMMONIA-BORANE ; SUPRAMOLECULAR STRUCTURE ; THERMAL-DECOMPOSITION ; BONDS ; RAMAN ; CRYSTAL ; CASTEP ; BH3NH3
语种英语
WOS记录号WOS:000379456800012
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/260285
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
作者单位中国科学院高能物理研究所
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GB/T 7714
Qi, GY,Wang, K,Li XD,et al. High Pressure Behavior of Hydrogen Storage Material Guanidinium Borohydride[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2016,120(25):13414-13420.
APA Qi, GY,Wang, K,李晓东,Li, XD,&Zou, B.(2016).High Pressure Behavior of Hydrogen Storage Material Guanidinium Borohydride.JOURNAL OF PHYSICAL CHEMISTRY C,120(25),13414-13420.
MLA Qi, GY,et al."High Pressure Behavior of Hydrogen Storage Material Guanidinium Borohydride".JOURNAL OF PHYSICAL CHEMISTRY C 120.25(2016):13414-13420.
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