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Spectral Properties and Energy Transfer between Ce3+ and Yb3+ in the Ca3Sc2Si3O12 Host: Is It an Electron Transfer Mechanism?
Zhou, L; Tanner, PA; Ning, LX; Zhou, WJ; Liang, HB; Zheng, LR; Zheng LR(郑黎荣)
2016
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY A
ISSN1089-5639
Volume120Issue:28Pages:5539-5548
SubtypeArticle
AbstractThe downshifting from Ce3+ blue emission to Yb3+ near-infrared emission has been studied in the garnet host Ca2.8-2xCe0.1YbxNa0.1+xSc2Si3O12 (x = 0-0.36). The downshifting does not involve quantum cutting, but one incident blue photon is transferred from Ce3+ to Yb3+ with an energy transfer efficiency up to 90% when x = 0.36 for the Yb3+ dopant ion. For x <= 0.15, a multiphonon-assisted electric dipole electric quadrupole mechanism of energy transfer dominates, while for the highest concentration of Yb3+ employed, the electron transfer mechanism is confirmed. A temperature-dependent increase of the Ce3+ -> Yb3+ energy transfer rate does not exclusively indicate the electron transfer mechanism. The application of the material to solar energy conversion is indicated.
DOI10.1021/acs.jpca.6b04641
WOS KeywordSOLIDS ; IONS ; INTERVALENCE ; LUMINESCENCE ; CRYSTALS ; STATES
Indexed BySCI ; ADS
Language英语
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000380590800014
ADS Bibcode2016JPCA..120.5539Z
ADS URLhttps://ui.adsabs.harvard.edu/abs/2016JPCA..120.5539Z
ADS CITATIONShttps://ui.adsabs.harvard.edu/abs/2016JPCA..120.5539Z/citations
Citation statistics
Cited Times:5 [ADS]
Document Type期刊论文
Identifierhttp://ir.ihep.ac.cn/handle/311005/260283
Collection中国科学院高能物理研究所
Affiliation中国科学院高能物理研究所
Recommended Citation
GB/T 7714
Zhou, L,Tanner, PA,Ning, LX,et al. Spectral Properties and Energy Transfer between Ce3+ and Yb3+ in the Ca3Sc2Si3O12 Host: Is It an Electron Transfer Mechanism?[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2016,120(28):5539-5548.
APA Zhou, L.,Tanner, PA.,Ning, LX.,Zhou, WJ.,Liang, HB.,...&郑黎荣.(2016).Spectral Properties and Energy Transfer between Ce3+ and Yb3+ in the Ca3Sc2Si3O12 Host: Is It an Electron Transfer Mechanism?.JOURNAL OF PHYSICAL CHEMISTRY A,120(28),5539-5548.
MLA Zhou, L,et al."Spectral Properties and Energy Transfer between Ce3+ and Yb3+ in the Ca3Sc2Si3O12 Host: Is It an Electron Transfer Mechanism?".JOURNAL OF PHYSICAL CHEMISTRY A 120.28(2016):5539-5548.
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