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Synthesis, Characterization and Performance of P3HT-Azide-PCBM Microgel
Wei, GM; Li, XX; Jia, D; Cheng, H; Cheng H(程贺)
2016
发表期刊JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷号16期号:6页码:5639-5645
通讯作者程贺
文章类型Article
摘要Spherical Poly(3-hexylthiophene)-azide-[6,6]-phenyl-C-61-butyric acid methyl ester (P3HT-azide-PCBM) microgel was synthesized by introducing an azide cross-linkable group into the conjugated polymer. Its UV-vis spectrum shifts blue as a result of the systematic disruption of planarity along the P3HT backbone and a reduction in long range conjugation. And the corresponding fluorescence spectrum also indicates that a strong intra-molecular photo-induced electron transfer is originated from the covalent linkage of PCBM moiety to the P3HT backbone via the hexyl bridge upon photoexcitation. Combined Gel Permeation Chromatography (GPC), dynamic and static light scattering (DLS and SLS) measurements prove that the resultant P3HT-azide-PCBM copolymer is a uniform spherical microgel with a hydrodynamic radius of 130 nm at room temperature. The spherical P3HT-azide-PCBM microgel can be used as electron donor or compatibilizer in bulk-heterojunction (BHJ) devices, but its introduction reduces the photovoltaic performance compared with the blend of P3HT/PCBM, because the hole mobility in the crosslinked polythiophene backbones is largely decreased.
关键词P3HT-Azide-PCBM Microgel Bulk Heterojunction Solar Cells Stability Nano-Morphology
学科领域Chemistry; Science & Technology - Other Topics; Materials Science; Physics
DOI10.1166/jnn.2016.12049
关键词[WOS]POLYMER SOLAR-CELLS ; PHOTOVOLTAIC CELLS ; MORPHOLOGICAL STABILIZATION ; ORGANIC PHOTOVOLTAICS ; DIBLOCK COPOLYMERS ; EFFICIENT ; C-60 ; POLY(3-HEXYLTHIOPHENE) ; ORGANIZATION ; NETWORK
收录类别SCI ; EI
语种英语
WOS类目Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000386123900029
引用统计
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/260188
专题东莞分部
实验物理中心
作者单位中国科学院高能物理研究所
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Wei, GM,Li, XX,Jia, D,et al. Synthesis, Characterization and Performance of P3HT-Azide-PCBM Microgel[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2016,16(6):5639-5645.
APA Wei, GM,Li, XX,Jia, D,Cheng, H,&程贺.(2016).Synthesis, Characterization and Performance of P3HT-Azide-PCBM Microgel.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,16(6),5639-5645.
MLA Wei, GM,et al."Synthesis, Characterization and Performance of P3HT-Azide-PCBM Microgel".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 16.6(2016):5639-5645.
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