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Phase transformation in nanocrystalline alpha-quartz GeO2 up to 51.5 GPa
Wang, H; Liu, JF; Wu, HP; He, Y; Chen, W; Wang, Y; Zeng, YW; Wang, YW; Luo, CJ; Liu, J; Hu, TD; Stahl, K; Jiang, JZ; Luo CJ(罗崇举); Liu J(刘景); Hu TD(胡天斗)
2006
Source PublicationJOURNAL OF PHYSICS-CONDENSED MATTER
Volume18Issue:48Pages:10817-10824
Corresponding AuthorZhejiang Univ, Dept Mat Sci & Engn, Lab New Struct Mat, Hangzhou 310027, Peoples R China ; Zhejiang Univ, Ctr Anal, Hangzhou 310027, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Beijing, Peoples R China ; Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark
SubtypeArticle
AbstractThe high-pressure behaviour of nanocrystalline alpha-quartz GeO2 (q-GeO2) with average crystallite sizes of 40 and 260 nm has been studied by in situ high-pressure synchrotron radiation x-ray diffraction measurements up to about 51.5 GPa at ambient temperature. Two phase transformations, q-GeO2 to amorphous GeO2 and amorphous GeO2 to monoclinic GeO2, are detected. The onset and end of the transition pressures for the q-GeO2-to-amorphous GeO2 phase transition are found to be approximately 10.8 and 14.9 GPa for the 40 nm q-GeO2 sample, and 9.5 and 12.4 GPa for the 260 nm q-GeO2 sample, respectively. The mixture of amorphous and monoclinic GeO2 phases remains up to 51.5 GPa during compression and even after pressure release. This result strongly suggests that the difference of free energy between the amorphous phase and the monoclinic phase might be small. Consequently, defects in the starting material, which alter the free energies of the amorphous phase and the monoclinic phase, may play a key role for the phase transformation of q-GeO2.
Subject AreaPhysics
DOI10.1088/0953-8984/18/48/008
URL查看原文
Indexed ByADS
Language英语
WOS Research AreaPhysics
WOS SubjectPhysics, Condensed Matter
WOS IDWOS:000242650600009
ADS Bibcode2006JPCM...1810817W
ADS URLhttps://ui.adsabs.harvard.edu/abs/2006JPCM...1810817W
ADS CITATIONShttps://ui.adsabs.harvard.edu/abs/2006JPCM...1810817W/citations
Citation statistics
Cited Times:4 [ADS]
Document Type期刊论文
Identifierhttp://ir.ihep.ac.cn/handle/311005/240174
Collection中国科学院高能物理研究所_技术发展与经营管理处
加速器中心
多学科研究中心
Affiliation中国科学院高能物理研究所
First Author AffilicationInstitute of High Energy
Recommended Citation
GB/T 7714
Wang, H,Liu, JF,Wu, HP,et al. Phase transformation in nanocrystalline alpha-quartz GeO2 up to 51.5 GPa[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2006,18(48):10817-10824.
APA Wang, H.,Liu, JF.,Wu, HP.,He, Y.,Chen, W.,...&胡天斗.(2006).Phase transformation in nanocrystalline alpha-quartz GeO2 up to 51.5 GPa.JOURNAL OF PHYSICS-CONDENSED MATTER,18(48),10817-10824.
MLA Wang, H,et al."Phase transformation in nanocrystalline alpha-quartz GeO2 up to 51.5 GPa".JOURNAL OF PHYSICS-CONDENSED MATTER 18.48(2006):10817-10824.
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