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Phase Behavior and Rheological Properties of Salt-Free Catanionic Surfactant Mixtures in the Presence of Bile Acids
Liu, CC; Hao, JC; Wu ZY(吴自玉); Wu, ZY
2010
发表期刊JOURNAL OF PHYSICAL CHEMISTRY B
卷号114期号:30页码:9795-9804
通讯作者[Liu, Changcheng ; Hao, Jingcheng] Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China ; [Wu, Ziyu] Chinese Acad Sci, Inst High Energy Phys, Beijing 100039, Peoples R China
文章类型Article
摘要The phase behavior, rheological properties, and structures of two salt-free catanionic surfactant systems, tetradecyltrimethylammonium hydroxide ((ITA)OH)/lauric acid (LA)/H(2)O and cetyltrimethylammonium hydroxide ((CTA)OH)/LA/H(2)O, in the presence of deoxycholic acid (DeCA) were investigated and compared with the results of cholic acid (CA). Small-angle X-ray scattering, deuterium nuclear magnetic resonance, and rheological measurements were employed to monitor the phase structure and transition. The surface tension was used to investigate the surface activities of the bile acid/(TTA)OH and bile acid/(TA)OH mixtures in dilute solutions. The results show that they have a minimum surface tension in a solution with excess cationic surfactant, and the critical micelle concentration decreases with an increase of the cationic surfactant chain length and hydrophobicity of the bile acids. At equimolar mixtures of DeCA and cationic surfactants, or DeCA being in excess, phase separation occurs with a large diameter of droplets in the upper phase and a small volume of viscous liquid in the bottom phase. Compared with CA systems, in the salt-free catanionic surfactant systems containing DeCA, phase transition from the birefringent L(alpha) phase to the L(1) phase occurs at a high molar fraction of DeCA, and the viscosity is higher at the same molar fraction of bile acid, indicating the significant influence of the molecule structures of bile acids despite only one hydroxyl group difference. Shear thickening is observed in the L(alpha) region, and a gradual evolvement of aggregates is predicted. Longer chain cationic surfactant can also increase the shear viscosity, which could be ascribed to the increase of the critical packing parameter, but with less influence on the phase transition.
学科领域Chemistry
研究领域[WOS]Chemistry ; Chemistry
DOI10.1021/jp103916a
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语种英语
研究领域[WOS]Chemistry ; Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000280361100010
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被引频次:21[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/240165
专题多学科研究中心
作者单位中国科学院高能物理研究所
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Liu, CC,Hao, JC,Wu ZY,et al. Phase Behavior and Rheological Properties of Salt-Free Catanionic Surfactant Mixtures in the Presence of Bile Acids[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2010,114(30):9795-9804.
APA Liu, CC,Hao, JC,吴自玉,&Wu, ZY.(2010).Phase Behavior and Rheological Properties of Salt-Free Catanionic Surfactant Mixtures in the Presence of Bile Acids.JOURNAL OF PHYSICAL CHEMISTRY B,114(30),9795-9804.
MLA Liu, CC,et al."Phase Behavior and Rheological Properties of Salt-Free Catanionic Surfactant Mixtures in the Presence of Bile Acids".JOURNAL OF PHYSICAL CHEMISTRY B 114.30(2010):9795-9804.
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