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Superconcentrated Hydrochloric Acid
Huang, K; Zhou, H; He, AQ; Sun, Y; Liu, YF; Gao, XX; Zhao, Y; Liu, SX; Li, ZH; Hu, TD; Li, XP; Liu, CG; Wei, YJ; Yang, LM; Feng, J; Cai, YL; Yang, ZL; Xu, YZ; Noda, I; Wu, JG; Li ZH(李志宏); Hu TD(胡天斗)
2011
发表期刊JOURNAL OF PHYSICAL CHEMISTRY B
卷号115期号:24页码:7823-7829
通讯作者[Sun, Yan ; Li, Xiaopei ; Liu, Cuige ; Wei, Yongju] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China ; [Huang, Kun ; Zhou, Hui ; He, Anqi ; Sun, Yan ; Liu, Yufeng ; Gao, Xiuxiang ; Liu, Shaoxuan ; Li, Xiaopei ; Yang, Zhanlan ; Xu, Yizhuang ; Wu, Jinguang] Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China ; [Zhou, Hui ; Cai, Yuanli] Soochow Univ, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Dept Polymer Sci & Engn, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China ; [Liu, Yufeng ; Zhao, Ying] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China ; [Li, Zhihong ; Hu, Tiandou] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China ; [Yang, Limin] Peking Univ, State Key Lab Nucl Phys & Technol, Inst Heavy Ion Phys, Sch Phys, Beijing 100871, Peoples R China ; [Feng, Juan] Univ Elect Sci & Technol China, Sch Life Sci & Technol, Chengdu 610054, Peoples R China ; [Noda, Isao] Procter & Gamble Co, W Chester, OH 45069 USA
文章类型Article
摘要We report the discovery of a potentially useful superconcentrated HCl at ambient temperature and pressure by using a simple surfactant-based reversed micelle system. Surprisingly, the molar ratios of H(+) to H(2)O (denoted as n(H+)/n(H2O)) in superconcentrated HCl can be larger than 5, while the maximum achievable n(H+)/n(H2O) value for conventional saturated HCl aqueous solution (37 wt %) is only about 0.28. Furthermore, both NMR and FT-IR results indicate that a significant amount of HCl remains in the molecular form rather than being ionized into H(+) and Cl(-). The superconcentrated HCl may promote some organic reactions that are not feasible by using conventional 37 wt % HCl solution. For example, addition reaction between C=C and HCl occurs in superconcentrated HCl solution without using catalysts.
学科领域Chemistry
研究领域[WOS]Chemistry ; Chemistry
DOI10.1021/jp109551z
URL查看原文
语种英语
研究领域[WOS]Chemistry ; Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000291709500013
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/240133
专题多学科研究中心
作者单位中国科学院高能物理研究所
推荐引用方式
GB/T 7714
Huang, K,Zhou, H,He, AQ,et al. Superconcentrated Hydrochloric Acid[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2011,115(24):7823-7829.
APA Huang, K.,Zhou, H.,He, AQ.,Sun, Y.,Liu, YF.,...&胡天斗.(2011).Superconcentrated Hydrochloric Acid.JOURNAL OF PHYSICAL CHEMISTRY B,115(24),7823-7829.
MLA Huang, K,et al."Superconcentrated Hydrochloric Acid".JOURNAL OF PHYSICAL CHEMISTRY B 115.24(2011):7823-7829.
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