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First Endohedral Metallofullerene-Containing Polymer: Preparation and Characterization of Gd@C-82-Polystyrene
Yue, DM; Bai, XJ; Zhao, SX; Miao, XP; Li, MX; Dong, JQ; Ibrahim, K; Wang, JO; Zhao, YL; Yuan, H; Xing, GM; Sun, BY; Zhao SX(赵世雄); Dong JQ(董金泉); Zhao YL(赵宇亮); Yuan H(袁慧); Xing GM(邢更妹); Sun BY(孙宝云); Kui RX(奎热西); Wang JO(王嘉鸥)
2010
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY C
Volume114Issue:17Pages:7631-7636
Corresponding Author[Yue, Dongmei ; Bai, Xiaojuan ; Zhao, Shixiong ; Dong, Jinquan ; Zhao, Yuliang ; Yuan, Hui ; Xing, Gengmei ; Sun, Baoyun] Chinese Acad Sci, Inst High Energy Phys, CAS Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China ; [Yue, Dongmei ; Bai, Xiaojuan] Beijing Univ Chem Technol, Beijing 100029, Peoples R China ; [Miao, Xiaopei ; Li, Meixian] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China ; [Ibrahim, Kurash ; Wang, Jiaou] CAS, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China
SubtypeArticle
AbstractMetallofullerene-containing copolymers (0.12, 0.20, 0.40, and 0.60 wt % Gd@C-82) were first synthesized via radical bulk copolymerization. The structures and the properties of the new polymers, Gd@C-82-PS, were investigated by GPC, UV-vis spectroscopy, FTIR, C-13 N-MR, CV/DPV, and XPS. The polymerization behavior of the metallofullerene and the properties of the Gd@C-82-PS polymers were different from those of C-60-PS and PS. Gd@C-82 exhibited a stronger radical-scavenging ability than that of hollow fullerenes in the polymerization. Molecular weights and the electron-accepting ability of the polymers were discussed and possible mechanisms of the influences were proposed.
Subject AreaChemistry; Science & Technology - Other Topics; Materials Science
DOI10.1021/jp9114578
URL查看原文
Indexed BySCI
Language英语
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:000277053600016
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Document Type期刊论文
Identifierhttp://ir.ihep.ac.cn/handle/311005/240128
Collection多学科研究中心
加速器中心
Affiliation中国科学院高能物理研究所
First Author AffilicationInstitute of High Energy
Recommended Citation
GB/T 7714
Yue, DM,Bai, XJ,Zhao, SX,et al. First Endohedral Metallofullerene-Containing Polymer: Preparation and Characterization of Gd@C-82-Polystyrene[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2010,114(17):7631-7636.
APA Yue, DM.,Bai, XJ.,Zhao, SX.,Miao, XP.,Li, MX.,...&王嘉鸥.(2010).First Endohedral Metallofullerene-Containing Polymer: Preparation and Characterization of Gd@C-82-Polystyrene.JOURNAL OF PHYSICAL CHEMISTRY C,114(17),7631-7636.
MLA Yue, DM,et al."First Endohedral Metallofullerene-Containing Polymer: Preparation and Characterization of Gd@C-82-Polystyrene".JOURNAL OF PHYSICAL CHEMISTRY C 114.17(2010):7631-7636.
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