On structural and high temperature electrochemical properties of ZrO2 thin film coating on Zr metal produced by carbonate melt
Zhang, XT; Zhang, RH; Hu, SM; Liu, T; Liu T(刘涛)
刊名JOURNAL OF MATERIALS SCIENCE
2007
卷号42期号:14页码:5632-5640
学科分类Materials Science
DOI10.1007/s10853-006-0746-8
通讯作者Chinese Acad Med Sci, Inst Mineral Resources, Open Res Lab Geochem Kinet, Beijing 100037, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Lab, Beijing, Peoples R China
文章类型Article
英文摘要Melt of NaCO3 can favor oxidation of Zr to form ZrO2 thin film on Zr surface, which is used to make Zr/ZrO2 oxidation/reduction electrode of pH sensor for testing elevated temperature aqueous solutions. Using SEM, EPMA, XPS, EXAFS and HRTEM, we found that ZrO2 film is tightness and solid with 20 mu m thickness composed by nanometer-sized monoclinic crystals. Zr/ZrO2 interface is characterized of zoning structure according to topography and chemical composition in five zones: oxygen-rich ZrO2, ZrO2, oxygen-rich Zr metal, oxygen-bearing Zr and Zr from outmost to center. Melt oxidation process of Zr involved oxidation time, air and temperature. The air is important effect on structural and electrochemical properties of ZrO2 thin film for making elevate temperature electrochemical sensor. If oxygen air largely presented in carbonate melting process, ZrO2 thin film is not tightness and not for oxidation/reduction electrode.
类目[WOS]Materials Science, Multidisciplinary
研究领域[WOS]Materials Science
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语种英语
WOS记录号WOS:000247943600049
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/240039
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
作者单位中国科学院高能物理研究所
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GB/T 7714
Zhang, XT,Zhang, RH,Hu, SM,et al. On structural and high temperature electrochemical properties of ZrO2 thin film coating on Zr metal produced by carbonate melt[J]. JOURNAL OF MATERIALS SCIENCE,2007,42(14):5632-5640.
APA Zhang, XT,Zhang, RH,Hu, SM,Liu, T,&刘涛.(2007).On structural and high temperature electrochemical properties of ZrO2 thin film coating on Zr metal produced by carbonate melt.JOURNAL OF MATERIALS SCIENCE,42(14),5632-5640.
MLA Zhang, XT,et al."On structural and high temperature electrochemical properties of ZrO2 thin film coating on Zr metal produced by carbonate melt".JOURNAL OF MATERIALS SCIENCE 42.14(2007):5632-5640.
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