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Electronic structure of MnS studied by resonant inelastic soft X-ray scattering
Zhou KJ(周克瑾); Cui MQ(崔明启); Ma CY(马陈燕); Zhao YD(赵屹东); Wu ZY(吴自玉); Zhou, KJ; Tezuka, Y; Cui, MQ; Ma, CY; Zhao, YD; Wu, ZY; Yagishita, A
Corresponding AuthorChinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China ; Hirosaki Univ, Fac Sci & Technol, Dept Adv Phys, Aomori 0368561, Japan ; High Energy Accelerator Res Organizat, Inst Mat Struct Sci, Photon Factory, Tsukuba, Ibaraki 3050801, Japan
AbstractThe electronic structure of MnS was studied using resonant inelastic soft X-ray scattering (RIXS) from 2p(6)3d(5)-> 2p(5)3d(6)-> 2p(6)3d(5) channel. The d-d excitation and charge-transfer ( CT) excitation were obtained which were resonant at excitation energies corresponding to L absorption edge and the satellites, respectively. RIXS and XAS spectra were simulated by Hartree-Fock method under atomic SO3 and cubic O-h symmetries. The crystal field 10Dq value was evaluated to 0.80 eV-0.85 eV. The stronger CT excitation of MnS than that of MnO originates from its narrower bandwidth.
Keywordresonant inelastic soft X-ray scattering soft X-ray absorption spectroscopy d-d excitation charge-transfer excitation
Subject AreaPhysics
WOS Research AreaPhysics
WOS SubjectPhysics, Multidisciplinary
WOS IDWOS:000246600400087
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Document Type期刊论文
First Author AffilicationInstitute of High Energy
Recommended Citation
GB/T 7714
Zhou KJ,Cui MQ,Ma CY,et al. Electronic structure of MnS studied by resonant inelastic soft X-ray scattering[J]. ACTA PHYSICA SINICA,2007,56(5):2986-2991.
APA 周克瑾.,崔明启.,马陈燕.,赵屹东.,吴自玉.,...&Yagishita, A.(2007).Electronic structure of MnS studied by resonant inelastic soft X-ray scattering.ACTA PHYSICA SINICA,56(5),2986-2991.
MLA 周克瑾,et al."Electronic structure of MnS studied by resonant inelastic soft X-ray scattering".ACTA PHYSICA SINICA 56.5(2007):2986-2991.
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