Formation of Ge-S bonds from AOT-Coated GeO2 nanoparticles at high temperature: An in situ heating EXAFS investigation
Chen X(陈兴); Cai Q(蔡泉); Wang W(王维); Mo G(默广); Jiang LS(江隆盛); Zhang KH(张坤浩); Chen ZJ(陈中军); Wu ZY(吴自玉); Wu ZH(吴忠华); Chen, X; Cai, Q; Wang, W; Mo, G; Jiang, LS; Zhang, KH; Chen, ZJ; Wu, ZY; Wu, ZH
刊名CHEMISTRY OF MATERIALS
2008
卷号20期号:8页码:2757-2762
学科分类Chemistry; Materials Science
DOI10.1021/cm703368u
通讯作者[Chen, Xing ; Cai, Quan ; Wang, Wei ; Mo, Guang ; Jiang, Longsheng ; Zhang, Kunhao ; Chen, Zhongjun ; Wu, Ziyu ; Wu, Zhonghua] CAS, Inst High Energy Phys, Beijing 100049, Peoples R China ; [Chen, Xing] Gen Res Inst Nonforrous Met, Beijing 100088, Peoples R China ; [Cai, Quan ; Wang, Wei ; Mo, Guang ; Jiang, Longsheng ; Zhang, Kunhao ; Wu, Ziyu ; Wu, Zhonghua] Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
文章类型Article
英文摘要Cubic germanium dioxide (GeO2) nanoparticles coated by sodium bis(2-ethylhexyl) sulfosuccinate (AOT) were synthesized with a reverse micelle technique. In situ heating extended X-ray absorption fine-structure technique was used to investigate the change of the local atomic structure and electronic structure around germanium. A direct formation of Ge-S bond was found from GeO2 at high temperature and ambient pressure. This Ge-S bond was identified to be temperature-dependent. The change of the local structure with heating is discussed. This study provides a routine process to synthesize GeS2 from GeO2 at higher temperature and ambient pressure.
类目[WOS]Chemistry, Physical ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Materials Science
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语种英语
WOS记录号WOS:000255019300025
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被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/239817
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
中国科学院高能物理研究所_实验物理中心
中国科学院高能物理研究所_多学科研究中心
作者单位中国科学院高能物理研究所
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Chen X,Cai Q,Wang W,et al. Formation of Ge-S bonds from AOT-Coated GeO2 nanoparticles at high temperature: An in situ heating EXAFS investigation[J]. CHEMISTRY OF MATERIALS,2008,20(8):2757-2762.
APA 陈兴.,蔡泉.,王维.,默广.,江隆盛.,...&Wu, ZH.(2008).Formation of Ge-S bonds from AOT-Coated GeO2 nanoparticles at high temperature: An in situ heating EXAFS investigation.CHEMISTRY OF MATERIALS,20(8),2757-2762.
MLA 陈兴,et al."Formation of Ge-S bonds from AOT-Coated GeO2 nanoparticles at high temperature: An in situ heating EXAFS investigation".CHEMISTRY OF MATERIALS 20.8(2008):2757-2762.
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