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Synthesis and Characterization of Metallofullerene Derivatives La@C-82-(C4N2H8)(m)H-n
Dai, FC; Chang, F; Ren TX(任同祥); Sun BY(孙宝云); Ren, TX; Sun, BY
2010
发表期刊CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
卷号31期号:10页码:1976-1981
通讯作者[Dai Fu-Cai ; Chang Fei] Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China ; [Ren Tong-Xiang ; Sun Bao-Yun] Chinese Acad Sci, CAS Key Lab Biomed Effects Nanomat & Nanosafety, Inst High Energy Phys, Beijing 100049, Peoples R China ; [Dai Fu-Cai] Langfang Teachers Coll, Coll Chem & Mat Sci, Langfang 065000, Peoples R China
文章类型Article
摘要Metallofullerene derivatives offer the opportunity to produce novel and advanced materials. In this work, we presented the synthesis of metallofullerene piperazine derivatives under different conditions by changing the temperature, light and ration of the reactants. Three metallofullerene piperazine derivatives [La@C-82-C4N2H8, La@C-82-C4N2H8-H-8, and La@C-82-(C4N2H8)(2)-H-6] were separated and confirmed by MALDI-TOF-MS, UV-Vis-NIR and FTIR. Compared with the hollow fullerene C-60, we found that metallofullerene showed higher reactivity than C-60 and produced different derivatives. The mechanism of the reaction was discussed.
关键词Metallofullerene Derivative MALDI-TOF-MS UV-Vis-NIR spectrum FTIR spectrum
学科领域Chemistry
研究领域[WOS]Chemistry ; Chemistry
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语种英语
研究领域[WOS]Chemistry ; Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000283634600014
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/239599
专题多学科研究中心
作者单位中国科学院高能物理研究所
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Dai, FC,Chang, F,Ren TX,et al. Synthesis and Characterization of Metallofullerene Derivatives La@C-82-(C4N2H8)(m)H-n[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2010,31(10):1976-1981.
APA Dai, FC,Chang, F,任同祥,孙宝云,Ren, TX,&Sun, BY.(2010).Synthesis and Characterization of Metallofullerene Derivatives La@C-82-(C4N2H8)(m)H-n.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,31(10),1976-1981.
MLA Dai, FC,et al."Synthesis and Characterization of Metallofullerene Derivatives La@C-82-(C4N2H8)(m)H-n".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 31.10(2010):1976-1981.
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