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The crystal structure and VUV luminescent property of the rare earth borates
Yang, Z; Ren, M; Lin, JH; Su, MZ; Tao, Y; Wang, W; Tao Y(陶冶); Wang W(王渭)
2000
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
Volume21Issue:9Pages:1339-1343
Corresponding AuthorPeking Univ, Dept Chem Mat, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China ; Yunnan Normal Univ, Dept Chem, Kunming 650092, Peoples R China ; Chinese Acad Sci, Beijing Synchrotron Radiat Lab, Inst High Energy Phys, Beijing 100039, Peoples R China
SubtypeArticle
AbstractThe VUV absorption of rare earth berates depends strongly on the structure of the berate ions. It is proposed from the simple extended Huckel calculation that the excitation transition in the VUV range is mainly from the B-O bonding orbital(HOMO) to the antibonding orbital(LUMO), The energy difference between the HOMO and LUMO decreases in the sequence of BO54->B2O54->BO33->B3O99-, which accords with the VUV experimental results.
Keywordrare earth borates VUV excitation spectra
Subject AreaChemistry
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Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000165111700002
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Document Type期刊论文
Identifierhttp://ir.ihep.ac.cn/handle/311005/239295
Collection中国科学院高能物理研究所_中国散裂中子源
实验物理中心
多学科研究中心
Affiliation中国科学院高能物理研究所
First Author AffilicationInstitute of High Energy
Recommended Citation
GB/T 7714
Yang, Z,Ren, M,Lin, JH,et al. The crystal structure and VUV luminescent property of the rare earth borates[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2000,21(9):1339-1343.
APA Yang, Z.,Ren, M.,Lin, JH.,Su, MZ.,Tao, Y.,...&王渭.(2000).The crystal structure and VUV luminescent property of the rare earth borates.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,21(9),1339-1343.
MLA Yang, Z,et al."The crystal structure and VUV luminescent property of the rare earth borates".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 21.9(2000):1339-1343.
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