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Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O
Shao, K; Ma, Y; Chen, ZH; Zhang, XT; He, T; Yao, JN; Liu, T; Zhang, J; Hu, TD; Liu T(刘涛); Zhang J(张静); Hu TD(胡天斗)
2001
发表期刊ACTA CHIMICA SINICA
卷号59期号:8页码:1335-1339
通讯作者Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China ; Chinese Acad Sci, Inst High Energet Phys, Beijing 100039, Peoples R China
摘要A novel photochromic compound NH3CH2CH2NH3Mo3O10.4.4H(2)O has been synthesized using ethylenediammonium cations as template under mild chemical conditions. Elemental analysis, TGA curve and IR spectra show that its inorganic framework is constructed from infinite chains of (Mo3O10)(infinity)(2-). Ethylenediammonium cations are bounded to the inorganic chain structure through a supramolecular interaction. It is found that this compound has good photochromic property. Differing from vacuum deposited MoO3 film, this compound turns from white to reddish brown after UV irradiation. EXAFS spectra confirm proton transfer from ethylenediammonium cations to Mo-O- after UV irradiation.
文章类型Article
关键词ethylenediammonium molybdate synthesis photochromic property
学科领域Chemistry
研究领域[WOS]Chemistry
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语种英语
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000170513100030
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文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/239289
专题多学科研究中心
作者单位中国科学院高能物理研究所
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GB/T 7714
Shao, K,Ma, Y,Chen, ZH,et al. Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O[J]. ACTA CHIMICA SINICA,2001,59(8):1335-1339.
APA Shao, K.,Ma, Y.,Chen, ZH.,Zhang, XT.,He, T.,...&胡天斗.(2001).Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O.ACTA CHIMICA SINICA,59(8),1335-1339.
MLA Shao, K,et al."Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O".ACTA CHIMICA SINICA 59.8(2001):1335-1339.
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