UNIV SCI & TECHNOL CHINA,HEFEI 230026,PEOPLES R CHINA
; CHINESE ACAD SCI,INST CHEM,BEIJING 100080,PEOPLES R CHINA
A variety of iron phosphide cluster ions were produced by laser ablation. It is indicated that the reaction between iron ion and neutral phosphorus cluster results in the production of these cluster ions, explaining qualitatively the odd-even variation of mass abundance. Also investigated were the properties of photolysis of these cluster ions at 248 nm which shows some basic units, FeP2+ and Fe2P+. or complexes composed of several basic units existing in larger cluster ions, based on which a chain structure of cluster ions was then formed. The above conclusions are supported by the theoretical calculation of the DV-X alpha method.
JU, X,SHI, CS,ZHANG, N,et al. ULTRAVIOLET PHOTOLYSIS AND FORMATION OF IRON PHOSPHIDE CLUSTER IONS[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY LIFE SCIENCES & EARTH SCIENCES,1995,38(10):1158-1165.
JU, X.,SHI, CS.,ZHANG, N.,GAO, Z.,KONG, FA.,...&唐孝威.(1995).ULTRAVIOLET PHOTOLYSIS AND FORMATION OF IRON PHOSPHIDE CLUSTER IONS.SCIENCE IN CHINA SERIES B-CHEMISTRY LIFE SCIENCES & EARTH SCIENCES,38(10),1158-1165.
JU, X,et al."ULTRAVIOLET PHOTOLYSIS AND FORMATION OF IRON PHOSPHIDE CLUSTER IONS".SCIENCE IN CHINA SERIES B-CHEMISTRY LIFE SCIENCES & EARTH SCIENCES 38.10(1995):1158-1165.