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Hydrothermal synthesis and thermal properties of a novel cubic ZrW1.80V0.20O7.90 solid solution
Chen, X; Deng, XB; Ma, H; Tao, JZ; Zhao, XH; Tao JZ(陶举洲)
2011
发表期刊JOURNAL OF SOLID STATE CHEMISTRY
卷号184期号:5页码:1090-1095
通讯作者[Chen, Xi ; Deng, Xuebin ; Ma, Hui ; Zhao, Xinhua] Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China ; [Chen, Xi ; Deng, Xuebin ; Ma, Hui ; Zhao, Xinhua] Beijing Normal Univ, Anal & Test Ctr, Beijing 100875, Peoples R China ; [Tao, Juzhou] Chinese Acad Sci, Inst High Energy Phys, Expt Phys Ctr, Beijing 100049, Peoples R China ; [Chen, Xi] N China Univ Water Source & Elect Power, Sch Civil Engn & Commun, Zhengzhou 450011, Peoples R China
文章类型Article
摘要Tetragonal ZrW1.80V0.20O6.90(OH)(2.00)(H2O)(2.00) hydrate was prepared using an acidic steam hydrothermal (ASH) method. Thermal dehydration followed by phase transformation of this precursor leads to successful synthesis of a novel W-site low-valent substituted cubic ZrW1.80V0.20O7.90 solid solution, the mechanism of this process is studied in detail revealing the hydrate and a metastable orthorhombic phase of V'(W)substitution solid solution as important intermediate product. This material is found to possess thermal contraction and order-disorder phase transformation properties similar to that of the cubic ZrW2O8. (C) 2011 Elsevier Inc. All rights reserved.
关键词Synthesis Solid solution Negative thermal expansion
学科领域Chemistry
研究领域[WOS]Chemistry ; Chemistry
DOI10.1016/j.jssc.2011.03.021
URL查看原文
语种英语
研究领域[WOS]Chemistry ; Chemistry
WOS类目Chemistry, Inorganic & Nuclear ; Chemistry, Physical
WOS记录号WOS:000290549900018
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被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/239032
专题实验物理中心
作者单位中国科学院高能物理研究所
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Chen, X,Deng, XB,Ma, H,et al. Hydrothermal synthesis and thermal properties of a novel cubic ZrW1.80V0.20O7.90 solid solution[J]. JOURNAL OF SOLID STATE CHEMISTRY,2011,184(5):1090-1095.
APA Chen, X,Deng, XB,Ma, H,Tao, JZ,Zhao, XH,&陶举洲.(2011).Hydrothermal synthesis and thermal properties of a novel cubic ZrW1.80V0.20O7.90 solid solution.JOURNAL OF SOLID STATE CHEMISTRY,184(5),1090-1095.
MLA Chen, X,et al."Hydrothermal synthesis and thermal properties of a novel cubic ZrW1.80V0.20O7.90 solid solution".JOURNAL OF SOLID STATE CHEMISTRY 184.5(2011):1090-1095.
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