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A novel spin transition compound with hysteresis [Fe(PhCH=Ntrz)(3)](BF4)(2)center dot 3H(2)O
Wu WF(吴卫芳); Wang, HM; Li, LC; Yang, GM; Liao, DZ; Yan, SP; Jiang, ZH; Wang, GL; Wang YB(王耘波)
1998
发表期刊CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
卷号19期号:7页码:1020-1022
通讯作者Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Beijing 100080, Peoples R China
文章类型Letter
摘要Spin transition complexes are of great interest because of their potential application in molecular based electronic devices such as optical memory and switches. A novel linear polynuclear spin transition complex [Fe (PhCH = Ntrz)(3)] (BF4)(2). 3H(2)O (where PhCH=Ntrz stood for the Schiff base condensed by 4-NH2-1, 2, 4-triazole and benzaldehyde) was synthesized and characterized by elemental analysis, molar conductance, IR and UV-Vis spectra, magnetic measurements and temperature-dependence optical detection. The spin transition occurred at 105 similar to 235 K with hysteresis and pronounced thermochromism, T-c up arrow =180 K, T-c down arrow =169 K, hysteresis width 11 K.
关键词iron(II) complex spin transition hysteresis thermochromism
学科领域Chemistry
研究领域[WOS]Chemistry ; Chemistry
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语种英语
研究领域[WOS]Chemistry ; Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000074925100003
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文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/238907
专题多学科研究中心
作者单位中国科学院高能物理研究所
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GB/T 7714
Wu WF,Wang, HM,Li, LC,et al. A novel spin transition compound with hysteresis [Fe(PhCH=Ntrz)(3)](BF4)(2)center dot 3H(2)O[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1998,19(7):1020-1022.
APA 吴卫芳.,Wang, HM.,Li, LC.,Yang, GM.,Liao, DZ.,...&王耘波.(1998).A novel spin transition compound with hysteresis [Fe(PhCH=Ntrz)(3)](BF4)(2)center dot 3H(2)O.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,19(7),1020-1022.
MLA 吴卫芳,et al."A novel spin transition compound with hysteresis [Fe(PhCH=Ntrz)(3)](BF4)(2)center dot 3H(2)O".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 19.7(1998):1020-1022.
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