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STM and XRD studies of the adsorption and assembling structures of phthalocyanine and porphyrin
Lei, SB; Wang, J; Dong, YH; Wang, C; Wan, LJ; Bai, CL
2002
发表期刊SURFACE AND INTERFACE ANALYSIS
卷号34期号:1页码:767-771
通讯作者Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Synchrotron Radiat Lab, Beijing 100080, Peoples R China
摘要Using scanning tunnelling microscopy (STM) and x-ray diffraction (XRD), the assembling behaviour of substituted phthalocyanine and porphyrin on both hydrophobic and hydrophilic surfaces was investigated. Copper (II) 2,3,9,10,16,17,23,24-octakis(octyloxy)-29H,31H-phthalocyanine (denoted as CuPcOC8) and 21,23-dihydro-5,10,15,20-tetrakis[4-(tetradecyloxy)phenyl]porphyrin (TTPP) molecules adsorb stably on a highly oriented pyrolytic graphite (HOPG) surface, yielding high-resolution STM images. The results illustrate that alkyl molecular anchors can be used as a generalized approach for immobilization of organic molecules on hydrophobic surfaces. The XRD results show that on a hydrophilic substrate CuPcOC8 and TTPP form completely different assembled structures from those on a HOPG surface, which indicates that the polarity of the substrate has substantial effects on the assembling behaviour of organic molecules. Copyright (C) 2002 John Wiley Sons, Ltd.
文章类型Article; Proceedings Paper
关键词STM and XRD studies phthalocyanine porphyrin assembly
学科领域Chemistry
研究领域[WOS]Chemistry
DOI10.1002/sia.1407
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语种英语
WOS类目Chemistry, Physical
WOS记录号WOS:000177885900168
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被引频次:24[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/238450
专题多学科研究中心
作者单位中国科学院高能物理研究所
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Lei, SB,Wang, J,Dong, YH,et al. STM and XRD studies of the adsorption and assembling structures of phthalocyanine and porphyrin[J]. SURFACE AND INTERFACE ANALYSIS,2002,34(1):767-771.
APA Lei, SB,Wang, J,Dong, YH,Wang, C,Wan, LJ,&Bai, CL.(2002).STM and XRD studies of the adsorption and assembling structures of phthalocyanine and porphyrin.SURFACE AND INTERFACE ANALYSIS,34(1),767-771.
MLA Lei, SB,et al."STM and XRD studies of the adsorption and assembling structures of phthalocyanine and porphyrin".SURFACE AND INTERFACE ANALYSIS 34.1(2002):767-771.
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