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A sulfur K-edge XANES study on the transfer of sulfur species in the reactive adsorption desulfurization of diesel oil over Ni/ZnO
Huang, LC; Wang, GF; Qin, ZF; Du, MX; Dong, M; Ge, H; Wu, ZW; Zhao, YD; Ma, CY; Hu, TD; Wang, J; Zhao YD(赵屹东); Ma CY(马陈燕); Hu TD(胡天斗)
2010
Source PublicationCATALYSIS COMMUNICATIONS
Volume11Issue:7Pages:592-596
Corresponding Author[Huang, Lichun ; Wang, Guofu ; Qin, Zhangfeng ; Du, Mingxian ; Dong, Mei ; Ge, Hui ; Wu, Zhiwei ; Wang, Jianguo] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China ; [Huang, Lichun ; Wu, Zhiwei ; Ma, Chenyan] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China ; [Zhao, Yidong ; Ma, Chenyan ; Hu, Tiandou] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China
SubtypeArticle
AbstractReactive adsorption desulfurization (RAIDS) of diesel oil was conducted over a Ni/ZnO adsorbent; the transfer of sulfur species in the RAIDS process was investigated by the sulfur K-edge X-ray absorption near-edge structure (XANES) and X-ray diffraction (XRD). The results indicted that the organic sulfur compounds in the diesel oil are first decomposed on surface Ni of Ni/ZnO to form Ni(3)S(2), followed by the reduction of Ni(3)S(2) to form H(2)S, and then H(2)S is stored in the adsorbent accompanied by the conversion of ZnO into ZnS. (C) 2010 Elsevier B.V. All rights reserved.
KeywordSulfur K-edge XANES XRD Sulfur species Ni/ZnO Reactive adsorption desulfurization Diesel oil
Subject AreaChemistry
DOI10.1016/j.catcom.2010.01.001
URL查看原文
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000275803100004
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Document Type期刊论文
Identifierhttp://ir.ihep.ac.cn/handle/311005/238056
Collection多学科研究中心
粒子天体物理中心
中国科学院高能物理研究所_中国散裂中子源
Affiliation中国科学院高能物理研究所
First Author AffilicationInstitute of High Energy
Recommended Citation
GB/T 7714
Huang, LC,Wang, GF,Qin, ZF,et al. A sulfur K-edge XANES study on the transfer of sulfur species in the reactive adsorption desulfurization of diesel oil over Ni/ZnO[J]. CATALYSIS COMMUNICATIONS,2010,11(7):592-596.
APA Huang, LC.,Wang, GF.,Qin, ZF.,Du, MX.,Dong, M.,...&胡天斗.(2010).A sulfur K-edge XANES study on the transfer of sulfur species in the reactive adsorption desulfurization of diesel oil over Ni/ZnO.CATALYSIS COMMUNICATIONS,11(7),592-596.
MLA Huang, LC,et al."A sulfur K-edge XANES study on the transfer of sulfur species in the reactive adsorption desulfurization of diesel oil over Ni/ZnO".CATALYSIS COMMUNICATIONS 11.7(2010):592-596.
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