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Dysprosium compounds studied by resonant inelastic X-ray scattering and high-resolution X-ray absorption near edge structure spectroscopy
Zhou KJ(周克瑾); Cui MQ(崔明启); Hua W(华巍); Ma CY(马陈燕); Zhao YD(赵屹东); Huang YY(黄宇营); He W(何伟); Wu ZY(吴自玉); Zhou, KJ; Cui, MQ; Hua, W; Ma, CY; Zhao, YD; Huang, YY; He, W; Wu, ZY
2008
Source PublicationSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume71Issue:2Pages:516-522
Corresponding Author[Zhou, K. J. ; Cui, M. Q. ; Hua, W. ; Ma, C. Y. ; Zhao, Y. D. ; Huang, Y. Y. ; He, W. ; Wu, Z. Y.] Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China
SubtypeArticle
AbstractA set of resonant inelastic X-ray scattering (RIXS) studies focusing on the 2p(6)4f(n) -> 2P(5)4f(n)5d(1)(2p(5)4f(n+1)5d(0)) -> 2p(6)3d(9)4f(n)5d(1)(2p(6)3d(9)4f(n+1)5d(0)) channel of dysprosium in Dy metal, Dy2O3, DyNi3 and Dy25Fe18 compounds have been carried out. Data showed with high statistics and resolution, the different delocalization degree of the 5d band of dysprosium in these compounds, e.g., decreasing from Dy metal to DyNi3, Dy25Fe18 and to dysprosium oxide, in agreement with the high-resolution XANES (HRXANES) spectra. Band structure calculations performed on Dy metal and Dy2O3 confirm both RIXS and HRXANES results in the increasing delocalization of the dysprosium 5d band in Dy metal with respect to Dy2O3. The 5d orbital occupancies of DyNi3 and Dy25Fe18 alloys have been also studied by comparison of the HRXANES white line (WL) area with the behavior of the final states energy position in RIXS spectra and we show that DyNi3 has a higher 5d orbital occupancy than Dy25Fe18. (C) 2008 Elsevier B.V. All rights reserved.
KeywordResonant inelastic X-ray scattering (RIXS) High-resolution XANES (HRXANES) Highly correlated dysprosium compounds Delocalization Orbital occupancy
Subject AreaSpectroscopy
DOI10.1016/j.saa.2007.11.033
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Indexed ByADS
Language英语
WOS Research AreaSpectroscopy
WOS SubjectSpectroscopy
WOS IDWOS:000261046200035
ADS Bibcode2008AcSpA..71..516Z
ADS URLhttps://ui.adsabs.harvard.edu/abs/2008AcSpA..71..516Z
ADS CITATIONShttps://ui.adsabs.harvard.edu/abs/2008AcSpA..71..516Z/citations
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Cited Times:0 [ADS]
Document Type期刊论文
Identifierhttp://ir.ihep.ac.cn/handle/311005/237787
Collection多学科研究中心
Affiliation中国科学院高能物理研究所
First Author AffilicationInstitute of High Energy
Recommended Citation
GB/T 7714
Zhou KJ,Cui MQ,Hua W,et al. Dysprosium compounds studied by resonant inelastic X-ray scattering and high-resolution X-ray absorption near edge structure spectroscopy[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2008,71(2):516-522.
APA 周克瑾.,崔明启.,华巍.,马陈燕.,赵屹东.,...&Wu, ZY.(2008).Dysprosium compounds studied by resonant inelastic X-ray scattering and high-resolution X-ray absorption near edge structure spectroscopy.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,71(2),516-522.
MLA 周克瑾,et al."Dysprosium compounds studied by resonant inelastic X-ray scattering and high-resolution X-ray absorption near edge structure spectroscopy".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 71.2(2008):516-522.
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