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The electronic structure of hexene on Ru(1010) surface
其他题名己烯在Ru(1010)表面价带电子特性研究
Zhang, JH; Zhuang, YY; Wu, Y; Bao, SN; Liu, FQ; Yipulaxin-Kuirexi; Qian, HJ; Liu FQ(刘凤琴); Kui RX(奎热西); Qian HJ(钱海杰)
2002
发表期刊ACTA PHYSICO-CHIMICA SINICA
卷号18期号:5页码:437-440
通讯作者Zhejiang Univ, Dept Phys, Hangzhou 310027, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Lab Synchrotron Radiat, Beijing 10039, Peoples R China
摘要The adsorption of hexene(C6H12) on Ru(1010) surface has been studied by the polarized angle-resolved ultra-violet photoemission spectroscope (ARUPS) and X-ray photoemission spectroscope (XPS). The results show that the hexene absorbs in a molecular state on the Ru (10 TO) surface below 200 K, the molecular orbits of pi(CC), sigma(CC) and pi(CH) were found at 7. 5, 9. 4 and 11. 1 eV respectively. The results of the polarized ARUPS show that the sigma(CC) orbit is symmetry about a mirror plane along <1210> azimuth but the pi(CC) orbit is anti-symmetry about a mirror plane. The results suggest that the hexene molecule lies in a plane along <1210> azimuth, With warming the substrate to 200 K the pi(CH) molecular orbit increases 0. 2 eV in binding energy, and the C is core level decreases 0. 3 eV in binding energy, the results suggest that dehydrogenated of hexene occurs at 200 K.
文章类型Article
关键词hexene dehydrogenated electronic structure
学科领域Chemistry
DOI10.3866/PKU.WHXB20020511
研究领域[WOS]Chemistry
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语种英语
WOS类目Chemistry, Physical
WOS记录号WOS:000175739600011
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文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/237483
专题多学科研究中心
作者单位中国科学院高能物理研究所
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GB/T 7714
Zhang, JH,Zhuang, YY,Wu, Y,et al. The electronic structure of hexene on Ru(1010) surface[J]. ACTA PHYSICO-CHIMICA SINICA,2002,18(5):437-440.
APA Zhang, JH.,Zhuang, YY.,Wu, Y.,Bao, SN.,Liu, FQ.,...&钱海杰.(2002).The electronic structure of hexene on Ru(1010) surface.ACTA PHYSICO-CHIMICA SINICA,18(5),437-440.
MLA Zhang, JH,et al."The electronic structure of hexene on Ru(1010) surface".ACTA PHYSICO-CHIMICA SINICA 18.5(2002):437-440.
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