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The structure and optical properties of the nanocrystalline ZnS films prepared by sulfurizing the as-deposited ZnO films
Zhang RG(张仁刚); Wang BY(王宝义); Zhang H(张会); Wei L(魏龙); Zhang, RG; Wang, BY; Zhang, H; Wei, L
2005
Source PublicationAPPLIED SURFACE SCIENCE
Volume241Issue:3-4Pages:435-441
Corresponding AuthorChinese Acad Sci, Inst High Energy Phys, Ley Lab Nucl Anal Techniques, Beijing 100039, Peoples R China
SubtypeArticle
AbstractThe nanocrystalline ZnS films are successfully produced by sulfidation of the as-deposited ZnO films of various sputtering time in the H2S-H-2-N-2 mixture. At the deposition time less than or equal to30 min, after 2 h sulfidation at 500 degreesC, the as-deposited ZnO films can be converted totally to the hexagonal ZnS films with a strongly (0 0 2) preferred orientation. However, the ZnS films converted from the 10-min deposited ZnO films have a poor crystallinity because of the great influence of the substrates on the properties of the films with the very small thickness. The good crystallinity, the high optical transparency of about 80% in the visible region and the band-gap energy of 3.68 eV are obtained for the ZnS films formed by sulfurizing the 30-min deposited ZnO films. In addition, it is found that the ZnS films produced by sulfurizing the as-deposited ZnO films almost have the same good crystallinity as those prepared by sulfurizing the annealed ZnO films, a reason for which is due to the strongly (0 0 2) preferred orientation during the growth of the ZnS films. This indicates that the ZnS films formed by sulfidation of the as-deposited ZnO films are suitable for use in the thin film solar cells. (C) 2004 Elsevier B.V. All rights reserved.
KeywordZnS sulfidation ZnO solar cells
Subject AreaChemistry; Materials Science; Physics
DOI10.1016/j.apsusc.2004.07.042
URL查看原文
Indexed ByADS
Language英语
WOS Research AreaChemistry ; Materials Science ; Physics
WOS SubjectChemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000227536800020
ADS Bibcode2005ApSS..241..435Z
ADS URLhttps://ui.adsabs.harvard.edu/abs/2005ApSS..241..435Z
ADS CITATIONShttps://ui.adsabs.harvard.edu/abs/2005ApSS..241..435Z/citations
Citation statistics
Cited Times:6 [ADS]
Document Type期刊论文
Identifierhttp://ir.ihep.ac.cn/handle/311005/237473
Collection多学科研究中心
Affiliation中国科学院高能物理研究所
First Author AffilicationInstitute of High Energy
Recommended Citation
GB/T 7714
Zhang RG,Wang BY,Zhang H,et al. The structure and optical properties of the nanocrystalline ZnS films prepared by sulfurizing the as-deposited ZnO films[J]. APPLIED SURFACE SCIENCE,2005,241(3-4):435-441.
APA 张仁刚.,王宝义.,张会.,魏龙.,Zhang, RG.,...&Wei, L.(2005).The structure and optical properties of the nanocrystalline ZnS films prepared by sulfurizing the as-deposited ZnO films.APPLIED SURFACE SCIENCE,241(3-4),435-441.
MLA 张仁刚,et al."The structure and optical properties of the nanocrystalline ZnS films prepared by sulfurizing the as-deposited ZnO films".APPLIED SURFACE SCIENCE 241.3-4(2005):435-441.
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