Effects of the sulfidation temperature on the structure, composition and optical properties of ZnS films prepared by sulfurizing ZnO films
Zhang RG(张仁刚); Wang BY(王宝义); Wan DY(万冬云); Wei L(魏龙); Zhang, RG; Wang, BY; Wan, DY; Wei, L
刊名OPTICAL MATERIALS
2004
卷号27期号:3页码:419-423
关键词ZnS sulfidation ZnO solar cells
学科分类Materials Science; Optics
DOI10.1016/j.optmat.2004.03.020
通讯作者Chinese Acad Sci, Inst High Energy Phys, Key Lab Nucl Anal Tech, Beijing 100039, Peoples R China
文章类型Article
英文摘要Nanocrystalline ZnS films have been prepared by sulfidation of the reactive magnetron sputtered ZnO films. The structure, composition and optical properties of the sulfurized ZnO films as a function of the sulfidation temperature (Ts) have been systematically studied. It is found that at Ts greater than or equal to 400degreesC ZnO is completely converted to ZnS with the hexagonal structure. The ZnS films have a strongly (002) preferred orientation and an optical transparency of about 80% in the visible region. In addition, at Ts < 444.6degreesC (boiling point of sulfur), some residual sulfur decomposed from H2S gas can adhere to the sulfurized film surface while at Ts = 580degreesC a S/Zn ratio much higher than the ideal stoichiometric proportion of ZnS is obtained for the ZnS films. ZnS films with a minimum XRD FWHM value of 0.165degrees and a good S/Zn ratio of 0.99 are obtained at a temperature of 500degreesC indicating the ZnS films to be suitable for use in the thin film solar cells. (C) 2004 Elsevier B.V. All rights reserved.
类目[WOS]Materials Science, Multidisciplinary ; Optics
研究领域[WOS]Materials Science ; Optics
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语种英语
WOS记录号WOS:000225675500011
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被引频次:12[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/237402
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
作者单位中国科学院高能物理研究所
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Zhang RG,Wang BY,Wan DY,et al. Effects of the sulfidation temperature on the structure, composition and optical properties of ZnS films prepared by sulfurizing ZnO films[J]. OPTICAL MATERIALS,2004,27(3):419-423.
APA 张仁刚.,王宝义.,万冬云.,魏龙.,Zhang, RG.,...&Wei, L.(2004).Effects of the sulfidation temperature on the structure, composition and optical properties of ZnS films prepared by sulfurizing ZnO films.OPTICAL MATERIALS,27(3),419-423.
MLA 张仁刚,et al."Effects of the sulfidation temperature on the structure, composition and optical properties of ZnS films prepared by sulfurizing ZnO films".OPTICAL MATERIALS 27.3(2004):419-423.
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