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Effect of pressure on the structural properties of Li[Li0.1Ni0.35Mn0.55]O-2
Zhang, YF; Wang, L; Yang, JP; He, XM; Wang, JX; Zhang, YL; Jin, YH; Li, YC; Xiong, L; Li YC(李延春); Xiong L(熊伦)
2015
发表期刊AIP ADVANCES
卷号5期号:4页码:47106
摘要Li-rich cathode material Li[Li0.1Ni0.35Mn0.55]O-2 was synthesized by a sol-gel method. The morphology and a-NaFeO2 type structure of the material at ambient conditions were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The high-pressure behavior of the material was studied at pressure up to 19.7 GPa by using angle dispersive synchrotron X-ray powder diffraction (ADXD). The studies affirmed that the a-NaFeO2 type structure existed up to at least 19.7 GPa. Rietveld refinement analysis indicated that the c/a lattice parameter ratio decreased and the Li-O bond length shrunk with the increasing pressure, however, the Li+/Ni2+ ions exchange increased under elevated pressure. The pressure-volume data of the material were fitted to the third-order Birch-Murnaghan equation of state and bulk modulus obtained upon compression from the fitting was 117 (1) GPa. (C) 2015 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.
文章类型Article
学科领域Science & Technology - Other Topics; Materials Science; Physics
DOI10.1063/1.4917297
收录类别SCI ; EI
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS记录号WOS:000353827700039
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/228554
专题多学科研究中心
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Zhang, YF,Wang, L,Yang, JP,et al. Effect of pressure on the structural properties of Li[Li0.1Ni0.35Mn0.55]O-2[J]. AIP ADVANCES,2015,5(4):47106.
APA Zhang, YF.,Wang, L.,Yang, JP.,He, XM.,Wang, JX.,...&熊伦.(2015).Effect of pressure on the structural properties of Li[Li0.1Ni0.35Mn0.55]O-2.AIP ADVANCES,5(4),47106.
MLA Zhang, YF,et al."Effect of pressure on the structural properties of Li[Li0.1Ni0.35Mn0.55]O-2".AIP ADVANCES 5.4(2015):47106.
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