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New Three-Fold Interpenetrated Uranyl Organic Framework Constructed by Terephthalic Acid and Imidazole Derivative
Chen F(陈飞); Wang CZ(王聪芝); Li ZJ(李子杰); Lan JH(蓝建慧); Chai ZF(柴之芳); Chen, F; Wang, CZ; Li, ZJ; Lan, JH; Ji, YQ; Chai, ZF
2015
发表期刊INORGANIC CHEMISTRY
卷号54期号:8页码:3829-3834
通讯作者柴之芳
摘要A new 3-fold interpenetrated uranyl organic framework, UO2(bdc)(dmpi), was hydrothermally synthesized using 1,4-benzenedicarboxylic acid (H2bdc) and 1-(4-(1H-imidazol-1-yl)-2,5-dimethylphenyl)-1H-imidazole (dmpi). This framework, which was determined by synchrotron radiation X-ray, exhibited a new 3-fold interpenetrated (2,4)-connected topology with the Schlafli symbol of (12(6))(12)(2). Additionally, large incurvation happened to the bond angle of [O=U=O](2+), which was always arranged in a rigorous line. Computational results based on density functional theory (DFT) indicated that the bent geometry of uranyl in UO2(bdc)(dmpi) was mainly due to the higher charge populations in the valence 6d shells of uranium, rendered by the electronegative imidazoles.
文章类型Article
学科领域Chemistry
DOI10.1021/acs.inorgchem.5b00013
收录类别SCI
WOS类目Chemistry, Inorganic & Nuclear
WOS记录号WOS:000353429500017
引用统计
被引频次:27[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/228522
专题院士
多学科研究中心
推荐引用方式
GB/T 7714
Chen F,Wang CZ,Li ZJ,et al. New Three-Fold Interpenetrated Uranyl Organic Framework Constructed by Terephthalic Acid and Imidazole Derivative[J]. INORGANIC CHEMISTRY,2015,54(8):3829-3834.
APA 陈飞.,王聪芝.,李子杰.,蓝建慧.,柴之芳.,...&Chai, ZF.(2015).New Three-Fold Interpenetrated Uranyl Organic Framework Constructed by Terephthalic Acid and Imidazole Derivative.INORGANIC CHEMISTRY,54(8),3829-3834.
MLA 陈飞,et al."New Three-Fold Interpenetrated Uranyl Organic Framework Constructed by Terephthalic Acid and Imidazole Derivative".INORGANIC CHEMISTRY 54.8(2015):3829-3834.
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