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Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports
Kang, XC; Shang, WT; Zhu, QG; Zhang, JL; Jiang, T; Han, BX; Wu, ZH; Li, ZH; Xing, XQ; Wu ZH(吴忠华); Li ZH(李志宏); Xing XQ(邢雪青)
2015
发表期刊CHEMICAL SCIENCE
卷号6期号:3页码:1668-1675
文章类型Article
摘要We proposed a strategy to synthesize mesoporous inorganic salt particles using the special properties of ionic liquid (IL) mixtures, and hollow mesoporous LaF3, NdF3, and YF3 particles were synthesized and characterized using different techniques. The size of the mesopores in the salt particles was about 4 nm, and the materials were full of crystal defects. The LaF3, NdF3 and YF3 particles were used as the catalysts for the cyanosilylation reaction of benzaldehyde using trimethylsilyl cyanide, and Ru/LaF3 and Ru/NdF3, in which Ru nanocatalysts were supported on the LaF3 and NdF3 particles with mesopores, were used to catalyze hydrogenations of benzene to cyclohexane and levulinic acid (LA) to g-valerolactone (GVL). It was discovered that the activities of these catalysts were unprecedentedly high for these reactions. Detailed study showed that both the crystal defects and the mesopores in the salt particles played crucial roles for the extremely high catalytic activity.
学科领域Chemistry
DOI10.1039/c4sc03736g
收录类别SCI ; EI
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000349832600008
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/228171
专题多学科研究中心
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GB/T 7714
Kang, XC,Shang, WT,Zhu, QG,et al. Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports[J]. CHEMICAL SCIENCE,2015,6(3):1668-1675.
APA Kang, XC.,Shang, WT.,Zhu, QG.,Zhang, JL.,Jiang, T.,...&邢雪青.(2015).Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports.CHEMICAL SCIENCE,6(3),1668-1675.
MLA Kang, XC,et al."Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports".CHEMICAL SCIENCE 6.3(2015):1668-1675.
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