Molecular-Level Insights into Intrinsic Peroxidase-Like Activity of Nanocarbon Oxides
Zhao RS(赵瑞生); Zhao, RS; Gao XF(高兴发); Zhao, X; Gao, XF
刊名CHEMISTRY-A EUROPEAN JOURNAL
2015
卷号21期号:3页码:960-964
关键词carboxyl density functional calculations nanocarbon oxides peroxidase reaction mechanism
学科分类Chemistry
DOI10.1002/chem.201404647
通讯作者高兴发
文章类型Article
英文摘要Nanocarbon oxides have been proved to possess great peroxidase-like activity, catalyzing the oxidation of many peroxidase substrates, such as 3,3,5,5-tetramethylbenzidine (TMB) and o-phenylenediamine dihydrochloride (OPD), accompanied by a significant color change. This chromogenic reaction is widely used to detect glucose and occult blood. The chromogenic reaction was intensively investigated with density functional theory and molecular-level insights into the nature of peroxidase-like activity were gained. A radical mechanism was unraveled and the carboxyl groups of nanocarbon oxides were identified as the reactive sites. Aromatic domains connected with the carboxyl groups were critical to the peroxidase-like activity.
类目[WOS]Chemistry, Multidisciplinary
收录类别SCI ; EI
WOS记录号WOS:000347615200002
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被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/228151
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
中国科学院高能物理研究所_多学科研究中心
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Zhao RS,Zhao, RS,Gao XF,et al. Molecular-Level Insights into Intrinsic Peroxidase-Like Activity of Nanocarbon Oxides[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(3):960-964.
APA 赵瑞生,Zhao, RS,高兴发,Zhao, X,&Gao, XF.(2015).Molecular-Level Insights into Intrinsic Peroxidase-Like Activity of Nanocarbon Oxides.CHEMISTRY-A EUROPEAN JOURNAL,21(3),960-964.
MLA 赵瑞生,et al."Molecular-Level Insights into Intrinsic Peroxidase-Like Activity of Nanocarbon Oxides".CHEMISTRY-A EUROPEAN JOURNAL 21.3(2015):960-964.
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