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Self-assembly and photoelectric properties of cerium complexes with 3,4,9,10-perylenetetracarboxylic acid on nanocrystalline TiO2 films
Wang, ZS; Huang, CH; Li, FY; Yang, SM; Weng, SF; Fu, XY; Wu, NZ; Kurash, I; Liu, FQ; Qian, HJ; Kui RX(奎热西); Liu FQ(刘凤琴); Qian HJ(钱海杰)
2001
发表期刊SCIENCE IN CHINA SERIES B-CHEMISTRY
卷号44期号:3页码:#REF!
通讯作者Huang, CH (reprint author), Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China.
文章类型Article
摘要Self-assembled (SA) films (PMP, M = Ce3+ or Ce4+) of 3,4,9,10-perylenetetracarboxylic acid (PTA) on nanocrystalline TiO2 films with Ce3+ or Ce4+ as a bridge were fabricated and characterized with UV-Vis, IR, and XPS synchrotron radiation photoelectron spectroscopy (SRPES) which gave the HOMO energy levels for the SA films. It was shown that thin-layer sandwich-type solar cells based on these SA films possess good properties for photoelectric conversion. While PTA-loaded TiO2 electrode (P) generated 26.9% of incident monochromatic photon-to-electron conversion efficiency (IPCE), PMP-sensitized TiO2 electrodes yielded 55.8% and 39.1% for Ce4+ and Ce3+ respectively. PMP films can be considered as a kind of complexes whose HOMO energy levels were proved to be higher than that of film P, which is one of the major reasons for the increase in IPCE from film P to film PMP.
关键词nanocrystalline TiO2 self-assembly perylenetetracarboxylic acid photoelectric conversion
学科领域Chemistry
DOI10.1007/BF02879617
收录类别SCI
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000169765500005
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/227300
专题多学科研究中心
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GB/T 7714
Wang, ZS,Huang, CH,Li, FY,et al. Self-assembly and photoelectric properties of cerium complexes with 3,4,9,10-perylenetetracarboxylic acid on nanocrystalline TiO2 films[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2001,44(3):#REF!.
APA Wang, ZS.,Huang, CH.,Li, FY.,Yang, SM.,Weng, SF.,...&钱海杰.(2001).Self-assembly and photoelectric properties of cerium complexes with 3,4,9,10-perylenetetracarboxylic acid on nanocrystalline TiO2 films.SCIENCE IN CHINA SERIES B-CHEMISTRY,44(3),#REF!.
MLA Wang, ZS,et al."Self-assembly and photoelectric properties of cerium complexes with 3,4,9,10-perylenetetracarboxylic acid on nanocrystalline TiO2 films".SCIENCE IN CHINA SERIES B-CHEMISTRY 44.3(2001):#REF!.
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