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Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex
Wang, ZS; Huang, CH; Huang, YY; Zhang, BW; Xie, PH; Hou, YJ; Ibrahim, K; Qian, HJ; Liu, FQ; Kui RX(奎热西); Qian HJ(钱海杰); Liu FQ(刘凤琴)
2002
发表期刊SOLAR ENERGY MATERIALS AND SOLAR CELLS
卷号71期号:2页码:#REF!
通讯作者Huang, CH (reprint author), Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China.
摘要The photoelectric behavior of a black dye, tris (isothiocyanato)-[N-(2,2':6', 2"-terpyridine-4-(4-carbuxylic acid) phenyl)] ruthenium (II) complex, was examined under different conditions. The dye was adsorbed on nanocrystalline TiO2 surface strongly and generated incident monochromatic photon-to-current conversion efficiency (IPCE) of about 90% at maximum absorption wavelength and greater than 20% in the near-IR region. A sandwich-type solar cell fabricated by this dye-sensitized nanocrystalline TiO2 film generated 6.1 mA cm(-2) of short-circuit photocurrent, 0.58 V of open-circuit photovoltage and 2.9% of overall yield under irradiation of white light (78,0 mW cm(-2)) from a Xe lamp. Since the title dye shows better photoresponse than the N3 dye in the near-IR region, it would be a promising panchromatic sensitizer after optimization. (C) 2002 Elsevier Science B.V. All rights reserved.
文章类型Article
关键词Gratzel cell black dye TiO2 nanocrystalline TiO2 dye sensitized solar cell terpyridyl ruthenium dyes photoelectrochemical solar cells
学科领域Energy & Fuels; Materials Science; Physics
DOI10.1016/S0927-0248(01)00085-X
收录类别SCI
WOS类目Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied
WOS记录号WOS:000173184700011
引用统计
被引频次:37[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/227258
专题多学科研究中心
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GB/T 7714
Wang, ZS,Huang, CH,Huang, YY,et al. Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS,2002,71(2):#REF!.
APA Wang, ZS.,Huang, CH.,Huang, YY.,Zhang, BW.,Xie, PH.,...&刘凤琴.(2002).Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex.SOLAR ENERGY MATERIALS AND SOLAR CELLS,71(2),#REF!.
MLA Wang, ZS,et al."Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex".SOLAR ENERGY MATERIALS AND SOLAR CELLS 71.2(2002):#REF!.
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