A study of the pre-edge X-ray absorption fine structures in Ni monoxide
Li SJ(李树军); Wu ZY(吴自玉); Hu TD(胡天斗); Xie YN(谢亚宁); Zhang J(张静); Liu T(刘涛); Li, SJ; Wu, ZY; Hu, TD; Xie, YN; Zhang, J; Liu, T; Natoli, CR; Paris, E; Marcelli, A
刊名PHYSICA SCRIPTA
2005
卷号T115页码:#REF!
学科分类Physics
通讯作者Wu, ZY (reprint author), Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, POB 918, Beijing 100039, Peoples R China.
文章类型Article
英文摘要Pre-edge features in the Ni K-edge X-ray absorption near-edge structure (XANES) spectrum of Ni monoxide (NiO) in octahedral coordination, were investigated. By comparing experimental data with dipolar and quadrupolar cross-section calculations in the framework of the full multiple-scattering theory we assign the first pre-edge peak to a direct quadrupolar transitions from the 1s core state to the 3d molecular orbitals of the central atom (due to the more effective attraction of the core hole). The intensity of quadrupolar transition is almost equal to the dipolar pre-edge structure, at higher energy, due to the hybridization between the p-orbitals of the central atom with the higher-shell metal octahedral orbitals, that reflects the density of states derived by the medium range order of the system.
类目[WOS]Physics, Multidisciplinary
收录类别SCI
WOS记录号WOS:000204272100058
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被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/227045
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
中国科学院高能物理研究所_多学科研究中心
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Li SJ,Wu ZY,Hu TD,et al. A study of the pre-edge X-ray absorption fine structures in Ni monoxide[J]. PHYSICA SCRIPTA,2005,T115:#REF!.
APA 李树军.,吴自玉.,胡天斗.,谢亚宁.,张静.,...&Marcelli, A.(2005).A study of the pre-edge X-ray absorption fine structures in Ni monoxide.PHYSICA SCRIPTA,T115,#REF!.
MLA 李树军,et al."A study of the pre-edge X-ray absorption fine structures in Ni monoxide".PHYSICA SCRIPTA T115(2005):#REF!.
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