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Methanol synthesis from CO2-rich syngas over a ZrO2 doped CuZnO catalyst
Yang, C; Ma, ZY; Zhao, N; Wei, W; Hu, TD; Sun, YH; Hu TD(胡天斗)
2006
发表期刊CATALYSIS TODAY
卷号115期号:1-4页码:#REF!
通讯作者Sun, YH (reprint author), Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China.
文章类型Article; Proceedings Paper
摘要ZrO2-doped CuZnO catalyst prepared by successive-precipitation method was investigated by ICP-AES, BET, TEM, XRD, EXAFS, H-2-TPR and CO/CO2 hydrogenation. The active phase of copper in CuZnO catalyst prepared by co-precipitation method was well-crystallized. The presence of ZrO2 led to a high copper dispersion, which was distinctive from CuZnO. Though the activity for carbon monoxide hydrogenation was little lower than that of CuZnO catalyst, ZrO2-doped CuZnO catalyst showed much higher activity and selectivity towards methanol synthesis from carbon dioxide hydrogenation. Moreover, ZrO2-doped-CuZnO catalyst showed high performance for methanol synthesis from CO2-rich syngas. (c) 2006 Elsevier B.V. All rights reserved.
关键词CuZnO catalyst ZrO2-doped CO/CO2 hydrogenation CO2-rich syngas methanol synthesis
学科领域Chemistry; Engineering
DOI10.1016/j.cattod.2006.02.077
收录类别SCI
WOS类目Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS记录号WOS:000238416100029
引用统计
被引频次:73[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/227031
专题多学科研究中心
推荐引用方式
GB/T 7714
Yang, C,Ma, ZY,Zhao, N,et al. Methanol synthesis from CO2-rich syngas over a ZrO2 doped CuZnO catalyst[J]. CATALYSIS TODAY,2006,115(1-4):#REF!.
APA Yang, C.,Ma, ZY.,Zhao, N.,Wei, W.,Hu, TD.,...&胡天斗.(2006).Methanol synthesis from CO2-rich syngas over a ZrO2 doped CuZnO catalyst.CATALYSIS TODAY,115(1-4),#REF!.
MLA Yang, C,et al."Methanol synthesis from CO2-rich syngas over a ZrO2 doped CuZnO catalyst".CATALYSIS TODAY 115.1-4(2006):#REF!.
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