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Effect of ionic liquid on the polarity and size of the reverse micelles in supercritical CO2
Li, JC; Zhang, JL; Han, BX; Gao, YN; Shen, D; Wu, ZH; Wu ZH(吴忠华)
2006
发表期刊COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷号279期号:1-3页码:#REF!
通讯作者Han, BX (reprint author), Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China.
文章类型Article
摘要The insoluble nature of ionic liquids (ILs) in SC CO2 provides excellent opportunity to study how very small amount of polar solvent affects the properties of reverse micelles in SC CO2. In this work, phase behavior study, UV-vis and small angle X-ray scattering (SAXS) techniques were used to invistigate the effect of IL, 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim] [BF4]), on the size and micropolarity (in the reverse micelles) of the reverse micelles formed by surfactant Surfynol-2502 (SF) in SC CO2. It is very interesting that the micropolarity and the size of the reverse micelles increase considerably with the increase of the amount of solubilized IL as its amount is extremely small. The results of this work provide some valuable information about how the solubilized polar solvent affect the properties of the reverse micelles as its amount is extremely small. (c) 2006 Elsevier B.V. All rights reserved.
关键词supercritical CO2 ionic liquid reverse micelles polarity size
学科领域Chemistry
DOI10.1016/j.colsurfa.2006.01.005
收录类别SCI
WOS类目Chemistry, Physical
WOS记录号WOS:000237907800026
引用统计
被引频次:21[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/226946
专题多学科研究中心
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GB/T 7714
Li, JC,Zhang, JL,Han, BX,et al. Effect of ionic liquid on the polarity and size of the reverse micelles in supercritical CO2[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2006,279(1-3):#REF!.
APA Li, JC.,Zhang, JL.,Han, BX.,Gao, YN.,Shen, D.,...&吴忠华.(2006).Effect of ionic liquid on the polarity and size of the reverse micelles in supercritical CO2.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,279(1-3),#REF!.
MLA Li, JC,et al."Effect of ionic liquid on the polarity and size of the reverse micelles in supercritical CO2".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 279.1-3(2006):#REF!.
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