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Oxidation of carbon monoxide and ethylene on Pd(001)-C(2x2)Mn
Wu, K; Zhai, RS; Jia, JF; Lu, SH; Wu, SC
1995
发表期刊JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
卷号76页码:#REF!
通讯作者Wu, K (reprint author), CHINESE ACAD SCI,DALIAN INST CHEM PHYS,STATE KEY LAB CATALYSIS,POB 110,DALIAN 116023,PEOPLES R CHINA.
文章类型Article; Proceedings Paper
摘要Oxidation of carbon monoxide and ethylene on an in situ prepared ordered Pd(001)-C(2x2)Mn alloy surface was investigated by LEED and HREELS. At 140 K, coadsorption of carbon monoxide and oxygen gives anew HREELS feature at 2300 cm(-1) which is tentatively assigned to the formation of adsorbed carbon dioxide with the molecular axis nearly perpendicular to the alloy surface. Meanwhile, ethylene reacts with oxygen on the ordered alloy surface at temperatures higher than 230 K to produce surface hydroxyl species and adsorbed CO. Bimetallic composition and the buckled structure of the alloy surface are responsible for the high reactivity and the stabilization of reaction intermediates in the two oxidation processes.
学科领域Spectroscopy
收录类别SCI
WOS类目Spectroscopy
WOS记录号WOS:A1995UC82800030
引用统计
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/226907
专题多学科研究中心
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GB/T 7714
Wu, K,Zhai, RS,Jia, JF,et al. Oxidation of carbon monoxide and ethylene on Pd(001)-C(2x2)Mn[J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA,1995,76:#REF!.
APA Wu, K,Zhai, RS,Jia, JF,Lu, SH,&Wu, SC.(1995).Oxidation of carbon monoxide and ethylene on Pd(001)-C(2x2)Mn.JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA,76,#REF!.
MLA Wu, K,et al."Oxidation of carbon monoxide and ethylene on Pd(001)-C(2x2)Mn".JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA 76(1995):#REF!.
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