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Systematic study of lanthanoid endohedral metallofullerenes: Production yields, HPLC retention time and reactor irradiation effects
Sueki, K; Akiyama, K; Zhao YL(赵宇亮); Zhao, YL; Ito, I; Ohkubo, Y; Kikuchi, K; Katada, M; Nakahara, H
2003
发表期刊JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
卷号255期号:1页码:#REF!
通讯作者Sueki, K (reprint author), Tokyo Metropolitan Univ, Grad Sch Sci, Hachioji, Tokyo 1920397, Japan.
摘要We made systematic studies of lanthanoid metallofullerenes on the following three properties using the radiochemical method: (1) the relative production yields of metallofullerene species, (2) variation of the HPLC retention time among M(III)@C-82 species, and (3) the effects of the reactor irradiation on the survival yields of each metallofullerene species. The production yields of M@C-82 relative to La@C-82 were found to decrease as the atomic number of M became larger and as the number of atom ratio, M/C, in the carbon rod became larger. On the other hand, the production yields of M1M2@C-82, relative to that of LuM@C-82 were found to increase for the larger atomic number. The retention time for the M(III)@C-82 species in the Buckyprep column was found to become slightly longer for the larger atomic number but it becomes abruptly larger for Gd, and Tb by about 5%. The overall effects of the reactor irradiation on the survival yields (or retention yields) of M@C-82 species were found to be (19.7+/-2.1)%.
文章类型Article
学科领域Chemistry; Nuclear Science & Technology
DOI10.1023/A:1022256520558
收录类别SCI
WOS类目Chemistry, Analytical ; Chemistry, Inorganic & Nuclear ; Nuclear Science & Technology
WOS记录号WOS:000180782100027
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被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/226580
专题多学科研究中心
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Sueki, K,Akiyama, K,Zhao YL,et al. Systematic study of lanthanoid endohedral metallofullerenes: Production yields, HPLC retention time and reactor irradiation effects[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2003,255(1):#REF!.
APA Sueki, K.,Akiyama, K.,赵宇亮.,Zhao, YL.,Ito, I.,...&Nakahara, H.(2003).Systematic study of lanthanoid endohedral metallofullerenes: Production yields, HPLC retention time and reactor irradiation effects.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,255(1),#REF!.
MLA Sueki, K,et al."Systematic study of lanthanoid endohedral metallofullerenes: Production yields, HPLC retention time and reactor irradiation effects".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 255.1(2003):#REF!.
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