Electrochemical synthesis of a ferrocenecarboxylic acid-C-60 composite and its electrocatalysis to hydrogen peroxide
Miao, XP; Liu, L; Wang, SK; Lin, H; Sun, BY; Hu, JB; Li, MX; Sun BY(孙宝云)
刊名ELECTROCHEMISTRY COMMUNICATIONS
2010
卷号12期号:1页码:#REF!
关键词C-60 Electrochemistry Ferrocenecarboxylic acid Electrocatalysis Hydrogen peroxide
学科分类Electrochemistry
DOI10.1016/j.elecom.2009.10.043
通讯作者Li, MX (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China.
文章类型Article
英文摘要A new ferrocenecarboxylic acid-C-60 composite (Fc-C-60) has been synthesized by controlled potential electrolysis. A composite modified glassy carbon electrode has been prepared based on its good electrochemical activity. The modified electrode in 0.1 M NaClO4 solution shows a reversible oxidation wave at E-1/2 = 0.32 V (vs. SCE) attributed to the oxidation of the ferrocene entity and a quasi-reversible reduction wave of C-60 entity at E-1/2 = -0.54 V (vs. SCE). Electrocatalytic studies show that Fc-C-60 at the modified electrode can mediate the reduction of hydrogen peroxide (H2O2), and a broad linear range from 1.2 mu M to 21.9 mM for H2O2 were obtained with a determination limit of 2.5 x 10(-7) M by amperometry. (C) 2009 Elsevier B.V. All rights reserved.
类目[WOS]Electrochemistry
收录类别SCI
WOS记录号WOS:000274233700022
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/226071
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
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Miao, XP,Liu, L,Wang, SK,et al. Electrochemical synthesis of a ferrocenecarboxylic acid-C-60 composite and its electrocatalysis to hydrogen peroxide[J]. ELECTROCHEMISTRY COMMUNICATIONS,2010,12(1):#REF!.
APA Miao, XP.,Liu, L.,Wang, SK.,Lin, H.,Sun, BY.,...&孙宝云.(2010).Electrochemical synthesis of a ferrocenecarboxylic acid-C-60 composite and its electrocatalysis to hydrogen peroxide.ELECTROCHEMISTRY COMMUNICATIONS,12(1),#REF!.
MLA Miao, XP,et al."Electrochemical synthesis of a ferrocenecarboxylic acid-C-60 composite and its electrocatalysis to hydrogen peroxide".ELECTROCHEMISTRY COMMUNICATIONS 12.1(2010):#REF!.
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