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OXIDATION OF ETHYLENE ON THE ORDERED ALLOY SURFACE PD(001)C(2X2)-MN
JIA, JF; WU, K; LU, SH; ZHAO, RG; WEI, XM; WU, SC; WANG, DZ
1995
发表期刊SURFACE SCIENCE
卷号338期号:1-3页码:#REF!
通讯作者JIA, JF (reprint author), ACAD SINICA,INST HIGH ENERGY PHYS,SYNCHROTRON RADIAT LAB,BEIJING 100039,PEOPLES R CHINA.
摘要Ethylene adsorption and coadsorption with oxygen on the ordered alloy surface Pd{001}c(2 X 2)-Mn were studied with high resolution electron energy loss spectroscopy (EELS). The vibrational spectrum for C2H4 adsorbed on Pd{001}c(2 X 2)-Mn at 140 K is similar to that for C2H4 adsorbed on Pd{001} at 80 K, which has been ascribed to di-sigma-bonded C2H4. In contrary to the observation on Pd(001), where oxygen preadsorption inhibits C2H4 by limiting the formation of di-sigma-bonded C2H4, on Pd{001}c(2 X 2)-Mn, the vibrational spectrum of C2H4 adsorbed at 140 K is not affected by the preadsorbed oxygen. At 230 K, the coadsorbed C2H4 and O-2 react with each other and form CO and H2O on the surface.
文章类型Article
关键词ALKENES ELECTRON ENERGY LOSS SPECTROSCOPY OXYGEN SURFACE CHEMICAL REACTION
学科领域Chemistry; Physics
DOI10.1016/0039-6028(95)00531-5
收录类别SCI
WOS类目Chemistry, Physical ; Physics, Condensed Matter
WOS记录号WOS:A1995RU49200018
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/225918
专题多学科研究中心
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GB/T 7714
JIA, JF,WU, K,LU, SH,et al. OXIDATION OF ETHYLENE ON THE ORDERED ALLOY SURFACE PD(001)C(2X2)-MN[J]. SURFACE SCIENCE,1995,338(1-3):#REF!.
APA JIA, JF.,WU, K.,LU, SH.,ZHAO, RG.,WEI, XM.,...&WANG, DZ.(1995).OXIDATION OF ETHYLENE ON THE ORDERED ALLOY SURFACE PD(001)C(2X2)-MN.SURFACE SCIENCE,338(1-3),#REF!.
MLA JIA, JF,et al."OXIDATION OF ETHYLENE ON THE ORDERED ALLOY SURFACE PD(001)C(2X2)-MN".SURFACE SCIENCE 338.1-3(1995):#REF!.
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