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The 4f5d configuration and VUV absorption of Pr3+ in YPO4
Huang, SH; You, FT; Meng, CX; Wang, DW; Tao, Y; Zhang, GB; Tao Y(陶冶)
2007
发表期刊JOURNAL OF LUMINESCENCE
卷号122页码:#REF!
通讯作者Huang, SH (reprint author), Beijing Jiaotong Univ, Key Lab Luminescence & Opt Informat, Inst Optoelect Technol, Beijing 100044, Peoples R China.
摘要Crystal field interaction of the 5d electron [H-CF(5d)] and the Coulomb interaction between the 5d and the 4f electrons [H-C(fd)] are the most important interactions in determining the structure of the 4f5d configuration of Pr3+ in solids. Energy levels of the 4f5d configuration in YPO4:Pr were calculated by diagonalizing the simplified Hamiltonian H-CF(5d) + H-C(fd). Coulomb exchange interaction compresses the extension of the triplet states, while expands that of the singlet states. Thus, for the triplet states, H-C(fd) could be considered approximately as a perturbation to H-CF(5d). Since the ground state of the 4 configuration is a triplet, the triplet state structure in the 4f5d configuration determines the spectroscopic properties of the ground state absorption. Absorption spectrum calculated by using the obtained 4f5d wave functions is comparable with the experimental ones. (c) 2006 Elsevier B.V. All rights reserved.
文章类型Article; Proceedings Paper
关键词Pr3+ 4f5d configuration VUV spectrum
学科领域Optics
DOI10.1016/j.jlumin.2006.01.071
收录类别SCI
WOS类目Optics
WOS记录号WOS:000242991900011
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/225579
专题多学科研究中心
推荐引用方式
GB/T 7714
Huang, SH,You, FT,Meng, CX,et al. The 4f5d configuration and VUV absorption of Pr3+ in YPO4[J]. JOURNAL OF LUMINESCENCE,2007,122:#REF!.
APA Huang, SH.,You, FT.,Meng, CX.,Wang, DW.,Tao, Y.,...&陶冶.(2007).The 4f5d configuration and VUV absorption of Pr3+ in YPO4.JOURNAL OF LUMINESCENCE,122,#REF!.
MLA Huang, SH,et al."The 4f5d configuration and VUV absorption of Pr3+ in YPO4".JOURNAL OF LUMINESCENCE 122(2007):#REF!.
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