Exploration of the Hydrogen-Bonded Energetic Material Carbohydrazide at High Pressures
Yan, TT; Wang, K; Tan, X; Liu, J; Liu, BB; Zou, B;刘景
刊名JOURNAL OF PHYSICAL CHEMISTRY C
2014
卷号118期号:40页码:22960-22967
学科分类Chemistry; Science & Technology - Other Topics; Materials Science
DOI10.1021/jp507748x
英文摘要We have reported the high-pressure behavior of hydrogen bonded energetic material carbohydrazide (CON4H6, CHZ) via in-situ Raman spectroscopy and angle dispersive X-ray diffraction (ADXRD) in a diamond anvil cell with similar to 15 GPa at room temperature. Significant changes in Raman spectra provide evidence for a pressue-induced structural phase transition in the range of similar to 8 to 10.5 GPa ADXRD experiments confirm this phase transition by symmetry transformation from P2(1)/n to a possible space group P (1) over bar, which exhibits similar to 23.1% higher density at 10.1 GPa compared to phase P2(1)/n at ambient pressure. Moreover, the observed transition is completely reversible when the pressure is totally released. On the basis of the decreased number of hydrogen bonds, the shortened hydrogen bond lengths, and the variations in the NH and NH2 stretching Raman peaks in the high pressure phase, we propose that this phase transition is caused by the rearrangement of the hydrogen-based networks.
收录类别SCI
WOS记录号WOS:000343016800016
引用统计
被引频次:17[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/225150
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
推荐引用方式
GB/T 7714
Yan, TT,Wang, K,Tan, X,et al. Exploration of the Hydrogen-Bonded Energetic Material Carbohydrazide at High Pressures[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2014,118(40):22960-22967.
APA Yan, TT,Wang, K,Tan, X,Liu, J,Liu, BB,&Zou, B;刘景.(2014).Exploration of the Hydrogen-Bonded Energetic Material Carbohydrazide at High Pressures.JOURNAL OF PHYSICAL CHEMISTRY C,118(40),22960-22967.
MLA Yan, TT,et al."Exploration of the Hydrogen-Bonded Energetic Material Carbohydrazide at High Pressures".JOURNAL OF PHYSICAL CHEMISTRY C 118.40(2014):22960-22967.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
11157.pdf(2554KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Yan, TT]的文章
[Wang, K]的文章
[Tan, X]的文章
百度学术
百度学术中相似的文章
[Yan, TT]的文章
[Wang, K]的文章
[Tan, X]的文章
必应学术
必应学术中相似的文章
[Yan, TT]的文章
[Wang, K]的文章
[Tan, X]的文章
相关权益政策
暂无数据
收藏/分享
文件名: 11157.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。