High-Pressure-Induced Polymorphic Transformation of Maleic Hydrazide
Wang, K; 刘景;Liu, J; Yang, K; Liu, BB; Zou, B
刊名JOURNAL OF PHYSICAL CHEMISTRY C
2014
卷号118期号:15页码:8122-8127
学科分类Chemistry; Science & Technology - Other Topics; Materials Science
DOI10.1021/jp500689w
英文摘要Maleic hydrazide, a unique example of polymorphic structures, was analyzed at pressure up to 5 GPa using in situ high-pressure Raman scattering and synchrotron X-ray diffraction techniques. Changes in the Raman spectra at 2 GPa indicate that a pressure-induced phase transition is occurring. The transition was further analyzed with angle dispersive X-ray diffraction, which demonstrated that maleic hydrazide underwent a polymorphic transformation from the form III to the form II. Moreover, the observed transformation was partially reversible when the system was brought back to ambient pressure. This work suggests that the high-pressure polymorphic transformation is caused by changes in the hydrogen-bonded ribbons which lead to supramolecular rearrangements in the crystal structure.
收录类别SCI
WOS记录号WOS:000334730300041
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被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/225140
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
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Wang, K,刘景;Liu, J,Yang, K,et al. High-Pressure-Induced Polymorphic Transformation of Maleic Hydrazide[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2014,118(15):8122-8127.
APA Wang, K,刘景;Liu, J,Yang, K,Liu, BB,&Zou, B.(2014).High-Pressure-Induced Polymorphic Transformation of Maleic Hydrazide.JOURNAL OF PHYSICAL CHEMISTRY C,118(15),8122-8127.
MLA Wang, K,et al."High-Pressure-Induced Polymorphic Transformation of Maleic Hydrazide".JOURNAL OF PHYSICAL CHEMISTRY C 118.15(2014):8122-8127.
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