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Enhanced soot combustion over partially substituted hydrotalcite-drived mixed oxide catalysts CoMgAlLaO
Dai, FF; Zhang, YX; Meng, M; Zhang, J; Zheng, LR; Hu, TD;张静; Zheng LR(郑黎荣); Hu TD(胡天斗)
2014
发表期刊JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷号393页码:68-74
摘要A series of hydrotalcite-derived multicomponent oxide catalysts Co2.5Mg0.5Al1-x%La-x%O (denoted as CMALa(x), x=0, 5, 8, 10 or 15) with different La contents were synthesized by co-precipitation, and employed for catalytic soot combustion and NOx storage at lean condition. It is found that the La-substituted catalysts are more active than the one without La for soot combustion and NOx storage. Among all the catalysts CMALa(x), CMALa(10) (x=10) exhibits the highest catalytic performance, showing the largest NOx storage capacity (300 mu mol/g) and the lowest temperature for the maximal soot oxidation rate (T-m = 388 degrees C). The results of H-2-TPR and O-2-TPD indicate that the La-substitution can enhance the redox properties and increase the amount of surface lattice oxygen species of the catalysts. The results of soot combustion kinetics show that the apparent activation energy of CMALa(10) is the lowest (92.75 kJ/mol). Based upon the catalytic performance and in situ DRIFTS characterization, a nitrate and/or NO2 enhanced soot combustion mechanism over CMALa(10) was proposed. It is revealed that at low temperature the stored nitrate can directly promote soot ignition, while at high temperature the NO2 species arising from NO oxidation or nitrate decomposition act as the main active species for soot combustion. (C) 2014 Elsevier B.V. All rights reserved.
关键词Hydrotalcite Lanthanum Soot combustion Nitrate Mechanism
学科领域Chemistry
DOI10.1016/j.molcata.2014.05.031
收录类别SCI
WOS记录号WOS:000341462700009
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/225118
专题多学科研究中心
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GB/T 7714
Dai, FF,Zhang, YX,Meng, M,et al. Enhanced soot combustion over partially substituted hydrotalcite-drived mixed oxide catalysts CoMgAlLaO[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2014,393:68-74.
APA Dai, FF.,Zhang, YX.,Meng, M.,Zhang, J.,Zheng, LR.,...&胡天斗.(2014).Enhanced soot combustion over partially substituted hydrotalcite-drived mixed oxide catalysts CoMgAlLaO.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,393,68-74.
MLA Dai, FF,et al."Enhanced soot combustion over partially substituted hydrotalcite-drived mixed oxide catalysts CoMgAlLaO".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 393(2014):68-74.
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