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Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)
Zhang, B; Zhang, Y; Chang GC(常广才); 高增强;Chang, GC; Gao, ZQ; Wang, DW; Zhu, DB
2014
发表期刊INORGANICA CHIMICA ACTA
卷号421页码:399-404
摘要Heterometallic yellow compound Ba-3[Fe(C2O4)(3)](2)(H2O)(12) (1) with mononuclear anion [Fe(C2O4)(3)(3-)] can be transformed to heterometallic red compound Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19) (2) with OH/O bridged tetranuclear anion [Fe4O(OH)(3)(C2O4)(8)(9-)] in the mother liquor. Ba2+ and Fe3+ form three-dimensional networks thorough oxalate anion and H2O molecules in 1 and 2. 1 is a paramagnet and a strong antiferromagnetic interaction as the ground state S = 0 exists in 2. (C) 2014 Elsevier B.V. All rights reserved.
关键词Iron Oxalate Hydroxo Oxo Magnetism
学科领域Chemistry
DOI10.1016/j.ica.2014.07.001
收录类别SCI
WOS记录号WOS:000341439300049
引用统计
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/225039
专题多学科研究中心
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GB/T 7714
Zhang, B,Zhang, Y,Chang GC,et al. Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)[J]. INORGANICA CHIMICA ACTA,2014,421:399-404.
APA Zhang, B.,Zhang, Y.,常广才.,高增强;Chang, GC.,Gao, ZQ.,...&Zhu, DB.(2014).Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19).INORGANICA CHIMICA ACTA,421,399-404.
MLA Zhang, B,et al."Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)".INORGANICA CHIMICA ACTA 421(2014):399-404.
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