| Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19) |
| Zhang, B; Zhang, Y; Chang GC(常广才) ; 高增强;Chang, GC; Gao, ZQ; Wang, DW; Zhu, DB
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| 2014
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| 发表期刊 | INORGANICA CHIMICA ACTA
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| 卷号 | 421页码:399-404 |
| 摘要 | Heterometallic yellow compound Ba-3[Fe(C2O4)(3)](2)(H2O)(12) (1) with mononuclear anion [Fe(C2O4)(3)(3-)] can be transformed to heterometallic red compound Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19) (2) with OH/O bridged tetranuclear anion [Fe4O(OH)(3)(C2O4)(8)(9-)] in the mother liquor. Ba2+ and Fe3+ form three-dimensional networks thorough oxalate anion and H2O molecules in 1 and 2. 1 is a paramagnet and a strong antiferromagnetic interaction as the ground state S = 0 exists in 2. (C) 2014 Elsevier B.V. All rights reserved. |
| 关键词 | Iron
Oxalate
Hydroxo
Oxo
Magnetism
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| 学科领域 | Chemistry
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| DOI | 10.1016/j.ica.2014.07.001
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| 收录类别 | SCI
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| WOS记录号 | WOS:000341439300049
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| 引用统计 |
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| 文献类型 | 期刊论文
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| 条目标识符 | http://ir.ihep.ac.cn/handle/311005/225039
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| 专题 | 多学科研究中心
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推荐引用方式
GB/T 7714 |
Zhang, B,Zhang, Y,Chang GC,et al. Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)[J]. INORGANICA CHIMICA ACTA,2014,421:399-404.
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| APA |
Zhang, B.,Zhang, Y.,常广才.,高增强；Chang, GC.,Gao, ZQ.,...&Zhu, DB.(2014).Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19).INORGANICA CHIMICA ACTA,421,399-404.
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| MLA |
Zhang, B,et al."Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)".INORGANICA CHIMICA ACTA 421(2014):399-404.
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