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Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions
Shang, WT; Kang, XC; Ning, H; Zhang, JL; Zhang, XG; Wu, ZH; Mo, G; Xing, XQ; Han, BX;吴忠华; Mo G(默广); Xing XQ(邢雪青)
2013
发表期刊LANGMUIR
卷号29期号:43页码:13168-13174
摘要In this work, the La-metal organic frameworks (La-MOFs) were synthesized using lanthanum(III) nitrate and 1,3,5-benzenetricarboxylic acid (BTC) in H2O-in-1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF(6)), bmimPF(6)-in-water, and the bicontinuous microemulsions stabilized by surfactant TX-100. The MOFs prepared were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and FT-IR methods, and the microstructures of the microemulsions in the H2O/bmimPF(6)/TX-100 system were studied by small-angle X-ray scattering (SXAS) technique. It was shown that the dispersed droplets in the water-in-bmimPF(6), bicontinuous and bmimPF6-in-water microemulsions were spherical, lamellar, and cylindrical, respectively. The shapes of the La-MOFs synthesized were similar to that of the droplets in the corresponding microemulsions. This indicated that the morphology of MOFs could be controlled by the microstructures of the microemulsions. On the basis of the systematic experimental results, the mechanism for controlling the morphology of the MOFs was proposed.
学科领域Chemistry; Materials Science
DOI10.1021/la402882a
收录类别SCI
WOS记录号WOS:000326429500008
引用统计
被引频次:33[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/224343
专题多学科研究中心
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GB/T 7714
Shang, WT,Kang, XC,Ning, H,et al. Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions[J]. LANGMUIR,2013,29(43):13168-13174.
APA Shang, WT.,Kang, XC.,Ning, H.,Zhang, JL.,Zhang, XG.,...&邢雪青.(2013).Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions.LANGMUIR,29(43),13168-13174.
MLA Shang, WT,et al."Shape and Size Controlled Synthesis of MOF Nanocrystals with the Assistance of Ionic Liquid Mircoemulsions".LANGMUIR 29.43(2013):13168-13174.
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